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Thermophysical Properties for Diethylene Glycol + Nitrobenzene and Triethylene Glycol + (Chloro-, Bromo-, Nitro-) Benzene Systems at Different Temperatures

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Abstract

The densities, viscosities, sound speeds, and relative permittivities for four binary mixtures of glycols+organic solvents that are miscible over the complete composition range, namely, diethylene glycol (DEG)+nitrobenzene and triethylene glycol (TEG)+chlorobenzene, +bromobenzene, and +nitrobenzene have been measured at atmospheric pressure and at temperatures from 298.15 to 313.15 K. The excess molar volumes are calculated and fitted with a Redlich–Kister type equation. The qualitative analysis of excess molar volumes revealed that the structure-making effects probably in the form of weak Cl· · ·H–O hydrogen bonding, Cl· · ·O electron acceptor–donor interactions, and interstitial accommodation of chlorobenzene in associate structures of triethylene glycol, etc. are predominant in these mixtures.

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Authors and Affiliations

  1. Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar, 388120, Gujarat, India

    Nandhibatla V. Sastry, Rakesh R. Thakor & Mitesh C. Patel

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  1. Nandhibatla V. Sastry
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  2. Rakesh R. Thakor
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  3. Mitesh C. Patel
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Correspondence to Nandhibatla V. Sastry.

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Sastry, N.V., Thakor, R.R. & Patel, M.C. Thermophysical Properties for Diethylene Glycol + Nitrobenzene and Triethylene Glycol + (Chloro-, Bromo-, Nitro-) Benzene Systems at Different Temperatures. Int J Thermophys 29, 610–618 (2008). https://doi.org/10.1007/s10765-008-0399-8

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  • DOI: https://doi.org/10.1007/s10765-008-0399-8

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