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Acoustic and Thermophysical Properties of Binary Liquid Mixtures of Primary Butanols with Hexane and Cyclohexane at 293.15 K

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Abstract

The experimental density and speed of ultrasound measurements, along with literature data, were used to calculate adiabatic and isothermal compressibility coefficients, the specific heat ratio, and isobaric thermal expansion coefficients for the binaries of 1-butanol with hexane and cyclohexane. They were also used to determine Beyer’s parameter of nonlinearity, B/A, and free intermolecular lengths, L. The free intermolecular lengths, L, calculated according to the Jacobson equation, were compared with values estimated from thermoacoustical parameters.

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Authors and Affiliations

  1. Institute of Chemistry, University of Silesia, Szkolna 9, Katowice, 40-006, Poland

    K. Bebek

  2. Department of Environmental Monitoring, Central Mining Institute, Gwarków 1, Katowice, 40-166, Poland

    A. Strugała-Wilczek

Authors
  1. K. Bebek
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  2. A. Strugała-Wilczek
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Correspondence to K. Bebek.

Additional information

Paper dedicated to Professor Dr. Stefan Ernst on the occasion of His 75th Birthday.

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Bebek, K., Strugała-Wilczek, A. Acoustic and Thermophysical Properties of Binary Liquid Mixtures of Primary Butanols with Hexane and Cyclohexane at 293.15 K. Int J Thermophys 31, 8–15 (2010). https://doi.org/10.1007/s10765-009-0665-4

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  • DOI: https://doi.org/10.1007/s10765-009-0665-4

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