Abstract
Excess molar volumes, \({V^{\rm E}_{ijk}}\), and speeds of sound, u ijk , of pyrrolidin-2-one (2-Py) (i)+benzene or methyl benzene (j)+propan-1-ol (k) ternary mixtures and speeds of sound, u ij , of benzene or methyl benzene (i)+propan-1-ol (j) binary mixtures have been measured dilatometrically and interferrometrically over the complete mole fraction range at 308.15 K. Speed-of-sound data have been utilized to evaluate excess isentropic compressibilities for binary and ternary mixtures. \({V^{\rm E}_{ijk}}\) and \({\left({\kappa_S^{\rm E}}\right)_{ijk}}\) values have been fitted to a Redlich–Kister equation to predict ternary adjustable parameters and standard deviations. Topological investigations employed for predicting excess molar volumes and excess isentropic compressibilities, \({\left({\kappa _S^{\rm E}} \right)_{ij}}\), of 2-Py + benzene or methyl benzene or propan-1-ol binary mixtures have been extended to ternary mixtures (by employing the concept of a connectivity parameter of third degree, 3 ξ, of a molecule) to obtain an expression that describes well the measured \({V^{\rm E}_{ijk}}\) and \({\left({\kappa_S^{\rm E}}\right)_{ijk}}\) values.
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Yadav, J.S., Sharma, D., Kumar, S. et al. Topological Investigations of Excess Molar Volumes and Excess Isentropic Compressibilities of Ternary Mixtures Containing Pyrrolidin-2-one at 308.15 K. Int J Thermophys 31, 2201–2215 (2010). https://doi.org/10.1007/s10765-010-0861-2
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DOI: https://doi.org/10.1007/s10765-010-0861-2