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Densities, Excess Molar Volumes, Ultrasonic Speeds, and Isentropic Compressibilities of Hexan-1-ol with 1,2-Dichloroethane, 1,2-Dibromoethane, and 1,1,2,2-Tetrachloroethene at (293.15 and 298.15) K

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Abstract

Densities, ρ, and ultrasonic speeds, u, of binary mixtures of hexan-1-ol with 1,2-dichloroethane, 1,2-dibromoethane, and 1,1,2,2-tetrachloroethene have been measured over the entire range of composition at (293.15 and 298.15) K and atmospheric pressure. From these data, the excess molar volumes, V E, deviations of ultrasonic speed, u D, from the ultrasonic speed of an ideal mixture, excess molar isentropic compressibilities, \({\kappa_{S,{\rm m}}^{\rm E}}\), intermolecular free lengths, L f, mean molecular radii, r, and thermal expansion coefficients, α, have been calculated. The experimental ultrasonic speeds have been analyzed in terms of Nomoto’s, Van Dael’s ideal mixture, and Junjie relations; Jacobson’s free length and Schaaffs’ collision factor theories; and thermoacoustical parameters.

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Authors and Affiliations

  1. Department of Chemistry, Kurukshetra University, Kurukshetra, 136119, India

    Subhash C. Bhatia, Rachna Bhatia & Gyan P. Dubey

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  1. Subhash C. Bhatia
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  2. Rachna Bhatia
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  3. Gyan P. Dubey
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Correspondence to Subhash C. Bhatia.

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Bhatia, S.C., Bhatia, R. & Dubey, G.P. Densities, Excess Molar Volumes, Ultrasonic Speeds, and Isentropic Compressibilities of Hexan-1-ol with 1,2-Dichloroethane, 1,2-Dibromoethane, and 1,1,2,2-Tetrachloroethene at (293.15 and 298.15) K. Int J Thermophys 31, 2119–2146 (2010). https://doi.org/10.1007/s10765-010-0874-x

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