Abstract
Speeds of sound, u ijk , of tetrahydropyran (THP) (i) + benzene (j) + toluene or o- or p-xylene (k), and tetrahydropyran (i)+toluene (j) + o- or p-xylene (k) ternary mixtures have been measured over the entire mole fraction range at 308.15 K and atmospheric pressure. The speed-of-sound data have been used to calculate isentropic compressibilities, \({(\kappa_S)_{ijk}}\) , and excess isentropic compressibilities, \({(\kappa_S^{\rm E})_{ijk}}\) . The \({(\kappa_S^{\rm E})_{ijk}}\) values for the investigated mixtures are correlated with the Redlich–Kister equation to estimate ternary adjustable parameters and standard deviations. The Moelwyn–Huggins concept (Huggins, Polymer 12:357, 1971) of interaction between the surfaces of components of binary mixtures has been extended to predict excess isentropic compressibilities of ternary mixtures by employing the concept of connectivity parameters of the third degree of a molecule (which in turn depends on its topology). It has been observed that \({(\kappa_S)_{ijk}}\) values predicted by the Moelwyn–Huggins concept compare well with corresponding experimental values.
Similar content being viewed by others
References
Inglese A., Wilhelm E., Grolier J.-P.E., Kehiaian H.V.: J. Chem. Thermodyn. 12, 217 (1980)
Wilhelm E., Inglese A., Grolier J.-P.E., Kehiaian H.V.: J. Chem. Thermodyn. 14, 33 (1982)
Inglese A., Grolier J.-P.E., Wilhelm E.: J. Chem. Eng. Data 28, 124 (1983)
Francesconi R., Comelli F.: J. Chem. Eng. Data 37, 230 (1992)
Sharma V.K., Romi , Kumar S.: Thermochim. Acta 417, 91 (2004)
Sharma V.K., Siwach R.K., Dimple: J. Chem. Thermodyn. 43, 39 (2011)
Sharma V.K., Romi: Can. J. Chem. 79, 1910 (2001)
Sharma V.K., Kumar S.: J. Solut. Chem. 34, 199 (2005)
Sharma D., Yadav J.S., Singh K.C., Sharma V.K.: J. Solut. Chem. 37, 1099 (2008)
Sharma D., Yadav J.S., Singh K.C., Sharma V.K.: J. Chem. Eng. Data. 54, 2109 (2009)
Brocos P., Amigo A., Pintos M., Calvo E., Bravo R.: Thermochim. Acta 286, 297 (1996)
Linstrom, P.J., Mallard, W.G. (eds): NIST Chemistry Webbook. Nat. Inst. Stand. Technol., Gaithersburg, MD (2009)
Riddick J.A., Bunger W.B., Skano T.K.: Organic Solvents Physical Properties and Methods of Purification, 4th edn. Wiley, New York (1986)
Valles C., Perez E., Cardoso M., Dominguez M., Mainar A.M.: J. Chem. Eng. Data 49, 1460 (2004)
Tamura K., Murakami S., Doi S.: J. Chem. Thermodyn. 17, 325 (1985)
Sehgal C.M., Porter B.R., Greenleaf J.F.: J. Acoust. Soc. Am. 79, 566 (1986)
Schaaf S.W.: Molecular Acoustics, New Series, Group II. Havdolt, London (1967)
Tardajos G., Diazpena M., Aircart E.: J. Chem. Thermodyn. 18, 683 (1968)
Siwach R.K., Dimple, Jangra S.K., Sharma V.K.: J. Solut. Chem. 39, 1492 (2010)
Benson G.C., Kiyohara O.: J. Chem. Thermodyn. 11, 1061 (1979)
Weast R.C.: CRC Handbook of Chemistry and Physics. CRC Press, Boca Raton, FL (1987)
Hildebrand J.H., Prausnitz J.M., Scott R.L.: Regular and Related Solutions. Van-Nonstand Reinheld Co., New York (1971)
Dimple, Ph.D. Thesis (Maharshi Dayanand University, Rohtak, Haryana, India, 2008)
Huggins M.L.: J. Phys. Chem. 74, 371 (1970)
Huggins M.L.: Polymer 12, 357 (1971)
Singh P.P., Bhatia M.: J. Chem. Soc. Faraday Trans. 1 85, 3807 (1989)
Singh P.P., Nigam R.K., Singh K.C., Sharma V.K.: Thermochim. Acta 46, 175 (1981)
Singh P.P., Sharma V.K., Sharma S.P.: Thermochim. Acta 106, 293 (1986)
Singh P.P.: Thermochim. Acta 66, 37 (1983)
Kier L.B., Yalkowasky S.H., Sinkula S.H., Valvani S.C.: Physico-Chemical Properties of Drugs. Mercel Dekker, New York (1980)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Siwach, R.K., Dimple & Sharma, V.K. Sound Speeds and Excess Isentropic Compressibilities of Ternary Mixtures of Tetrahydropyran and Aromatic Hydrocarbons at 308.15 K. Int J Thermophys 32, 1188–1201 (2011). https://doi.org/10.1007/s10765-011-0997-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10765-011-0997-8