Abstract
Densities, \(\rho \), viscosities, \(\eta \), speeds of sound, \(u\), and refractive indices, \(n_\mathrm{D} \), of binary liquid mixtures of 2-ethyl-1-hexanol with benzene, chlorobenzene, and bromobenzene have been measured over the entire range of composition at 298.15 K, 303.15 K, and 308.15 K and at atmospheric pressure. From the experimental data of the density, speed of sound, viscosity, and refractive index, the values of the excess molar volume, \(V^\mathrm{E}\), isentropic compressibility, \({\kappa _{S}}\), and deviations in molar refraction, \(\Delta R\), have been calculated. The viscosity data have been correlated using McAllister’s three-body interaction model at different temperatures. The calculated excess and deviation functions have been analyzed in terms of molecular interactions and structural effects.
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Acknowledgments
Authors are grateful to the Kurukshetra University authorities for providing the necessary facilities to carry out the research work and to the University Grants Commission, New Delhi for the award of a Senior Research Fellowship to one of the authors (Jasbir Sangwan).
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Bhatia, S.C., Sangwan, J., Rani, R. et al. Densities, Viscosities, Speeds of Sound, and Refractive Indices of Binary Mixtures of 2-Ethyl-1-hexanol with Benzene and Halobenzenes. Int J Thermophys 34, 2076–2088 (2013). https://doi.org/10.1007/s10765-013-1526-8
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DOI: https://doi.org/10.1007/s10765-013-1526-8