Skip to main content
SpringerLink
Log in

Isobaric Heat Capacity, Isothermal Compressibility and Fluctuational Properties of 1-Bromoalkanes

  • Published:
International Journal of Thermophysics Aims and scope Submit manuscript

Abstract

We present results of the experimental measurements of the isobaric heat capacity for 1-bromohexane, 1-bromoheptane, 1-bromooctane, 1-bromononane, 1-bromodecane, 1-bromoundecane, 1-bromododecane and 1-bromotetradecane at normal pressure and the speed of sound and the density for 1-bromotetradecane within the temperature range 298.15–423.15 K. These data on the isobaric heat capacity and the literature-based reference data for the density and the speed of sound were used to calculate the isothermal compressibility and the inverse reduced fluctuations. Based on the comparison of the results for pure n-alkanes and \(\alpha ,\omega \)-dibromoalkanes, we discuss the influence of bromine atom on the volume fluctuations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. A.J. Matheson, Molecular Acoustics (Wiley, New York, 1971)

    Google Scholar 

  2. U. Kaatze, F. Eggers, K. Lautscham, Meas. Sci. Technol. 19, 062001 (2008)

    Article  ADS  Google Scholar 

  3. R.D. Weir, T.W. de Loos (eds.), Measurement of the Thermodynamic Properties of Multiple Phases (Elsevier, Amsterdam, 2005)

    Google Scholar 

  4. A.L. Goncharov, V.V. Melent’ev, E.B. Postnikov, Eur. Phys. J. B 86, 357 (2013)

    Article  ADS  Google Scholar 

  5. M.G. Martin, J.I. Siepmann, J. Phys. Chem. B 102, 2569 (1998)

    Article  Google Scholar 

  6. C.A. Cerdeiriña, D. González-Salgado, L. Romaní, M. del Carmen Delgado, L.A. Torres, M. Costas, J. Chem. Phys. 120, 6648 (2004)

  7. Y.A. Neruchev, M.F. Bolotnikov, High Temp. 46, 40 (2008)

    Article  Google Scholar 

  8. S. Ernst, M. Chora̧żewski, M. Tkaczyk, P. Góralski, Fluid Phase Equilib. 174(1), 33 (2000)

  9. M.F. Bolotnikov, Y.A. Neruchev, O.S. Ryshkova, J. Chem. Eng. Data 52, 1065 (2007)

    Article  Google Scholar 

  10. O.S. Ryshkova, Y.A. Neruchev, High Temp. 47, 664 (2009)

    Article  Google Scholar 

  11. M.F. Bolotnikov, Y.A. Neruchev, O.S. Ryshkova, Y.E. Shevchenko, J. Chem. Eng. Data 54, 1716 (2009)

    Article  Google Scholar 

  12. M. Chora̧żewski, M. Skrzypek, Int. J. Thermophys. 31, 26 (2010)

  13. M. Chora̧żewski, E.B. Postnikov, Int. J. Thermal Sci. 90, 62 (2015)

  14. Y.A. Neruchev, O.S. Ryshkova, V.I. Korotkovskii, A.E. Lebedev, S.Y. E., GSSSD ME 197 (State Service of Standard Reference Data: Experimental Techniques, 197) (Moscow: STANDARTINFORM) (2012)

  15. G. Höhne, W.F. Hemminger, H.J. Flammersheim, Differential Scanning Calorimetry (Springer, Berlin, 2013)

    Google Scholar 

  16. The NIST Chemistry WebBook provides access to data compiled and distributed by NIST under the Standard Reference Data Program, http://webbook.nist.gov

  17. Y.A. Neruchev, M.F. Bolotnikov, V.V. Zotov, High Temp. 43, 266 (2005)

    Article  Google Scholar 

  18. Y.A. Neruchev, V.V. Zotov, V.N. Verveiko, G.A. Mel’nikov, Y.F. Melikhov, M.V. Verveiko, GSSSD ME 155 (State Service of Standard Reference Data: Experimental Techniques, 155) (STANDARTINFORM, Moscow, 2009)

    Google Scholar 

  19. M. Chora̧żewski, P. Góralski, M. Tkaczyk, J. Chem. Eng. Data 50, 619 (2005)

  20. L. Becker, O. Aufderhaar, J. Gmehling, J. Chem. Eng. Data 45, 661 (2000)

    Article  Google Scholar 

  21. E.B. Postnikov, A.L. Goncharov, V.V. Melentv, Int. J. Thermophys. 35(11), 2115 (2014)

    Article  ADS  Google Scholar 

  22. P.J. Flory, R.A. Orwoll, A. Vrij, J. Am. Chem. Soc. 86, 3507 (1964)

    Article  Google Scholar 

  23. T.K. Zahariev, R.I. Slavchov, A.V. Tadjer, A.N. Ivanova, J. Comput. Chem. 35, 776 (2014)

    Article  Google Scholar 

  24. M. Chora̧żewski, E.B. Postnikov, K. Oster, I. Polishuk, Ind. Eng. Chem. Res. 54, 9645 (2015)

  25. E.B. Bagley, T.P. Nelson, J.W. Barlow, S.A. Chen, Ind. Eng. Chem. Fundam. 9, 93 (1970)

    Article  Google Scholar 

  26. V.N. Kartsev, S.N. Shtykov, K.E. Pankin, D.V. Batov, J. Struct. Chem. 53, 1087 (2012)

    Article  Google Scholar 

  27. Y. Marcus, Chem. Rev. 113, 6536 (2013)

    Article  Google Scholar 

  28. H.V. Kehiaian, Fluid Phase Equilib. 13, 243 (1983)

    Article  Google Scholar 

Download references

Acknowledgments

We are grateful to the participants of 11th Winter Workshop on Molecular Acoustics, Relaxation and Calorimetric Methods (03-06.03.2015, Szczyrk, Poland), where the preliminary version of this work has been presented, for fruitful discussions. The work is supported by RFBR, research project No. 16-08-01203.

Author information

Authors and Affiliations

  1. Laboratory of Molecular Acoustics, Kursk State University, Radishcheva st., 33, Kursk, Russia, 305000

    V. I. Korotkovskii, O. S. Ryshkova & Yu. A. Neruchev

  2. Department of Theoretical Physics, Kursk State University, Radishcheva st., 33, Kursk, Russia, 305000

    A. L. Goncharov & E. B. Postnikov

Authors
  1. V. I. Korotkovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. S. Ryshkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. A. Neruchev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. L. Goncharov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. B. Postnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. B. Postnikov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Korotkovskii, V.I., Ryshkova, O.S., Neruchev, Y.A. et al. Isobaric Heat Capacity, Isothermal Compressibility and Fluctuational Properties of 1-Bromoalkanes. Int J Thermophys 37, 58 (2016). https://doi.org/10.1007/s10765-016-2064-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10765-016-2064-y

Keywords

Search

Navigation