Abstract
Semiclathrate hydrates are water-based host-guest compounds formed from aqueous solutions of ionic guest substances. These materials can greatly moderate formation pressures and temperatures from canonical gas hydrates. This is a significant advantage for industrial applications such as gas separation and storage. \(\hbox {N}_{2}\) gas is a major component contained in various flue gases and is usually mixed with \(\hbox {CO}_{2}\). Semiclathrate hydrates can separate these gases under moderate thermodynamic conditions. Tetra-n-butylammonium bromide (TBAB) is a widely used ionic guest substance. To develop the application technologies and their theoretical models, solubility data of \(\hbox {N}_{2}\) gas in TBAB aqueous solutions are required. In this study, we report \(\hbox {N}_{2}\) gas solubility measured by an absolute gravimetric method for the semiclathrate hydrate formation system of \(\hbox {TBAB} + \hbox {H}_{2}\hbox {O} + \hbox {N}_{2}\). The measurement pressures, temperatures and TBAB mass fractions were 3 MPa, 5 MPa and 7 MPa, 292.15 K, 302.15 K and 307.15 K, and 0 (pure water), 0.10, 0.20, 0.32 and 0.40, respectively. The uncertainties were 0.056 MPa, 0.44 K and 0.00012 in mole fraction. Although the technical difficulty lays on measurements of small \(\hbox {N}_{2}\) gas solubility by the absolute gravimetric method, our data implied the unique gas dissolution property of aqueous TBAB solution depending on the TBAB concentration. The aqueous TBAB solutions with mass fractions of 0.10 and 0.20 had similar \(\hbox {N}_{2}\) gas solubility as that in pure water. With higher mass fractions, 0.32 and 0.40, the \(\hbox {N}_{2}\) gas solubility slightly increased from that in pure water, which implies the salting-in effect of TBAB.
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References
G.A. Jeffrey, in Inclusion Compounds, vol. 1, ed. by J.L. Atwood, J.E.D. Davies, D.D. MacNicol (Academic Press, London, 1984), pp. 159–177
S. Muromachi, K.A. Udachin, K. Shin, S. Alavi, I.L. Moudrakovski, R. Ohmura, J.A. Ripmeester, Chem. Commun. 50, 11476 (2014)
S. Muromachi, K.A. Udachin, S. Alavi, R. Ohmura, J.A. Ripmeester, Chem. Commun. 52, 52621 (2016)
J. Douzet, M. Kwaterski, A. Lallemand, F. Chauvy, D. Flick, J.-M. Herri, Int. J. Refrig. 36, 1616 (2013)
P. Zhang, Z.W. Ma, R.Z. Wang, Renew. Sustain. Energ. Rev. 14, 598 (2010)
A. Chapoy, R. Anderson, B. Tohidi, J. Am. Chem. Soc. 129, 746 (2007)
W. Shimada, T. Ebinuma, H. Oyama, Y. Kamata, S. Takeya, T. Uchida, J. Nagao, Jpn. J. Appl. Phys. 42, L129 (2003)
N.H. Duc, F. Chauvy, J.-M. Herri, Energy Convers. Manag. 48, 1313 (2007)
S. Fan, S. Li, J. Wang, X. Lang, Y. Wang, Energy Fuel 23, 4202 (2009)
D. Zhong, P. Englezos, Energy Fuel 26, 2098 (2012)
P. Babu, W.I. Chin, R. Kumar, P. Linga, Ind. Eng. Chem. Res. 53, 4878 (2014)
N. Ye, P. Zhang, J. Chem. Eng. Data 59, 2920 (2014)
S. Muromachi, H. Hashimoto, T. Maekawa, Y. Yamamoto, S. Takeya, Fluid Phase Equilib. 413, 249 (2015)
A. van Cleeff, G.A.M. Diepen, Rec. Trav. Chim. 79, 582 (1960)
D.R. Marshall, S. Saito, R. Kobayashi, AIChE J. 10, 202 (1964)
J. Jhaveri, D.B. Robinson, Can. J. Chem. Eng. 43, 75 (1965)
K. Yasuda, Y. Oto, R. Shen, T. Uchida, R. Ohmura, J. Chem. Thermodyn. 67, 143 (2013)
M. Arjmandi, A. Chapoy, B. Tohidi, J. Chem. Eng. Data 52, 153 (2007)
N. Ye, P. Zhang, J. Chem. Eng. Data 57, 1557 (2012)
S. Lee, S. Park, Y. Lee, J. Lee, H. Lee, Y. Seo, Langmuir 27, 10597 (2011)
Y.A. Dyadin, K.A. Udachin, J. Struct. Chem. 28, 75 (1987)
H. Oyama, W. Shimada, T. Ebinuma, Y. Kamata, S. Takeya, T. Uchida, J. Nagao, H. Narita, Fluid Phase Equilib. 234, 131 (2005)
W. Shimada, M. Shiro, H. Kondo, S. Takeya, H. Oyama, T. Ebinuma, H. Narita, Acta Crystallogr. C 61, o65 (2005)
Y. Jin, J. Nagao, J. Phys. Chem. C 117, 6924 (2013)
Y. Jin, M. Kida, J. Nagao, J. Chem. Eng. Data 61, 679 (2016)
B. Chazallon, M. Ziskind, Y. Carpentier, C. Focsa, J. Phys. Chem. B 118, 13440 (2014)
D.W. Davidson, in Water: A Comprehensive Treatise, vol. 2, ed. by F. Franks (Plenum Press, New York, 1973), pp. 128–146
S. Fan, S. Li, J. Wang, X. Lang, Y. Wang, Energy Fuels 23, 4202 (2009)
S. Li, S. Fan, J. Wang, X. Lang, D. Liang, J. Nat. Gas. Chem. 18, 15 (2009)
X.-S. Li, H. Zhan, C.-G. Xu, Z.-Y. Zeng, Q.-N. Lv, K.-F. Yan, Energy Fuels 26, 2518 (2012)
Z.W. Ma, P. Zhang, H.S. Bao, S. Deng, Renew. Sustain. Energy Rev. 53, 1273 (2016)
F. Wang, S. Fu, G. Guo, Z.-Z. Jia, S.-J. Luo, A.-B. Guo, Energy 104, 76 (2016)
S. Fan, X. Long, X. Lang, Y. Wang, J. Chen, Energy Fuels 30, 8529 (2016)
H. Hashimoto, T. Yamaguchi, T. Kinoshita, S. Muromachi, Energy 129, 292 (2017)
S. Takeya, S. Muromachi, T. Maekawa, Y. Yamamoto, H. Mimachi, T. Kinoshita, T. Murayama, H. Umeda, D.-H. Ahn, Y. Iwasaki, H. Hashimoto, T. Yamaguchi, K. Okaya, S. Matsuo, Energies 10, 927 (2017)
P. Paricaud, J. Phys. Chem. B 115, 288 (2011)
M. Kwaterski, J.-M. Herri, Fluid Phase Equilib. 37, 22 (2014)
W. Lin, D. Dalmazzone, W. Fürst, A. Delahaye, L. Fournaison, P. Clain, J. Chem. Eng. Data 58, 2233 (2013)
S. Muromachi, A. Shijima, H. Miyamoto, R. Ohmura, J. Chem. Thermodyn. 85, 94 (2015)
International Organization for Standardization (ISO), Guide to the Expression of Uncertainty in Measurement (Geneva, Switzerland) (1993)
M.E. Wieser, N. Holden, T.B. Coplen, J.K. Böhlke, M. Berglund, W.A. Brand, P. De Bièvre, M. Gröning, R.D. Loss, J. Meija, T. Hirata, T. Prohaska, R. Schoenberg, G. O’Connor, T. Walczyk, S. Yoneda, X.-K. Zhu, Pure Appl. Chem. 85, 1047 (2013)
R. Sander, Henry’s Law Constants, in ed. by P.J. Linstrom, W.G. Mallard. NIST Chemistry WebBook, NIST Standard Reference Database Number 69. National Institute of Standards and Technology, Gaithersburg MD, 20899, http://webbook.nist.gov
S. Mao, A. Duan, Fluid Phase Equilib. 248, 103 (2006)
Acknowledgements
We thank Atsushi Shijima, Shogo Azumano, Shiro Suzuki and Ryota Bamba for their technical support for the experiments, and Joseph English for proofreading.
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Muromachi, S., Miyamoto, H. & Ohmura, R. Solubility of Nitrogen Gas in Aqueous Solution of Tetra-n-Butylammonium Bromide. Int J Thermophys 38, 173 (2017). https://doi.org/10.1007/s10765-017-2310-y
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DOI: https://doi.org/10.1007/s10765-017-2310-y