Abstract
A sulfur cathode with enhanced electrochemical properties is prepared by a hydrogel binder owning three-dimensional polymeric network for Li–S batteries. The promising high-performance binder (Alg-Ca2+) is constructed by an in situ interconnection of alginate chains by additive divalent cation with a facile and self-assembly strategy. With the assistance of 3D network, the sulfur/activated carbon composite cathode exhibits a higher rate capability and cycling performance compared to poly(vinylidene fluoride) binder, and the capacity retention is up to 80.6 % after 200 cycles (0.5C, 1C = 1675 mA g−1). Additionally, the electrochemical impedance spectroscopy also reveals a lower electrode resistance and better kinetic characteristics with Alg-Ca2+ as a binder. The improved electrochemical behaviors are assigned to the ability of maintaining the electrode stability due to the excellent mechanical property and amorphous structure.
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Bruce PG, Freunberger SA, Hardwick LJ, Tarascon JM (2012) Li–O2 and Li–S batteries with high energy storage. Nat Mater 11:19–29
Yin YX, Xin S, Guo YG, Wan LJ (2013) Lithium–sulfur batteries: electrochemistry, materials, and prospects. Angew Chem Int Chem 52:13186–13200
Chen R, Zhao T, Wu F (2015) From a historic review to horizons beyond: lithium–sulphur batteries run on the wheels. Chem Commun 51:18–33
Bresser D, Passerini S, Scrosati B (2013) Recent progress and remaining challenges in sulfur-based lithium secondary batteries—a review. Chem Commun 49:10545–10562
Xu G, Ding B, Pan J, Nie P, Shen L, Zhang X (2014) High performance lithium–sulfur batteries: advances and challenges. J Mater Chem A 2:12662–12676
Li L, Ruan G, Peng Z, Yang Y, Fei H, Raji AR, Samuel EL, Tour JM (2014) Enhanced cycling stability of lithium sulfur batteries using sulfur-polyaniline-graphene nanoribbon composite cathodes. ACS Appl Mater Interfaces 6:15033–15039
Ji L, Rao M, Aloni S, Wang L, Cairns EJ, Zhang Y (2011) Porous carbon nanofiber-sulfur composite electrodes for lithium/sulfur cells. Energy Environ Sci 4:5053–5059
Ji L, Rao M, Zheng H, Zhang L, Li Y, Duan W, Guo J, Cairns EJ, Zhang YG (2011) Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells. J Am Chem Soc 133:18522–18525
Zhou W, Xiao X, Cai M, Yang L (2014) Polydopamine-coated, nitrogen-doped, hollow carbon–sulfur double-layered core–shell structure for improving lithium–sulfur batteries. Nano Lett 14:5250–5256
Ji X, Evers S, Black R, Nazar LF (2011) Stabilizing lithium–sulphur cathodes using polysulphide reservoirs. Nat Commun 2:325
Seh ZW, Li W, Cha JJ, Zheng G, Yang Y, McDowell MT, Hsu PC, Cui Y (2013) Sulphur–TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries. Nat Commun 4:1331
Wei H, Ma J, Li B, Zuo Y, Xia D (2014) Enhanced cycle performance of lithium–sulfur batteries using a separator modified with a PVDF-C layer. ACS Appl Mater Interfaces 6:20276–20281
Zhang SS, Tran DT, Zhang Z (2014) Poly(acrylic acid) gel as a polysulphide blocking layer for high performance lithium/sulphur battery. J Mater Chem A 2:18288–18292
Wang C, Su K, Wan W, Guo H, Zhou H, Chen J, Zhang X, Huang Y (2014) High sulfur loading composite wrapped by 3D nitrogen-doped graphene as a cathode material for lithium–sulfur batteries. J Mater Chem A 2:5018–5023
Wang Z, Dong Y, Li H, Zhao Z, Wu HB, Hao C, Liu S, Qiu J, Lou XW (2014) Enhancing lithium–sulphur battery performance by strongly binding the discharge products on amino-functionalized reduced graphene oxide. Nat Commun 5:5002
Gu M, Lee J, Kim Y, Kim JS, Jang BY, Lee KT, Kim B-S (2014) Inhibiting the shuttle effect in lithium–sulfur batteries using a layer-by-layer assembled ion-permselective separator. RSC Adv 4:46940–46946
Chou SL, Pan Y, Wang JZ, Liu HK, Dou SX (2014) Small things make a big difference: binder effects on the performance of Li and Na batteries. Phys Chem Chem Phys 16:20347–20359
Song J, Xu T, Gordin ML, Zhu P, Lv D, Jiang Y-B, Chen Y, Duan Y, Wang D (2014) Nitrogen-doped mesoporous carbon promoted chemical adsorption of sulfur and fabrication of high-areal-capacity sulfur cathode with exceptional cycling stability for lithium–sulfur batteries. Adv Funct Mater 24:1243–1250
Manthiram A, Fu Y, Chung SH, Zu C, Su YS (2014) Rechargeable lithium–sulfur batteries. Chem Rev 114:11751–11787
Lacey MJ, Jeschull F, Edström K, Brandell D (2014) Porosity blocking in highly porous carbon black by PVdF binder and its implications for the li–s system. J Phys Chem C 118:25890–25898
Bao W, Zhang Z, Gan Y, Wang X, Lia J (2013) Enhanced cyclability of sulfur cathodes in lithium–sulfur batteries with Na-alginate as a binder. J Energy Chem 22:790–794
Sun J, Huang YQ, Wang WK, Yu ZB, Wang AB, Yuan KG (2008) Application of gelatin as a binder for the sulfur cathode in lithium–sulfur batteries. Electrochim Acta 53:7084–7088
He M, Yuan LX, Zhang WX, Hu XL, Huang YH (2011) Enhanced cyclability for sulfur cathode achieved by a water-soluble binder. J Phys Chem C 115:15703–15709
Wang J, Yao Z, Monroe CW, Yang J, Nuli Y (2013) Carbonyl-β-cyclodextrin as a novel binder for sulfur composite cathodes in rechargeable lithium batteries. Adv Funct Mater 23:1194–1201
Zhang ZA, Zeng T, Lu H, Jia M, Li J, Lai YQ (2012) Enhanced high-temperature performances of LiFePO4 cathode with polyacrylic acid as binder. ECS Electrochem Lett 1:A74–A76
Liu J, Zhang Q, Wu ZY, Wu JH, Li JT, Huang L, Sun SG (2014) A high-performance alginate hydrogel binder for the Si/C anode of a Li–ion battery. Chem Commun 50:6386–6389
Zhang L, Zhang L, Chai L, Xue P, Hao W, Zheng H (2014) A coordinatively cross-linked polymeric network as a functional binder for high-performance silicon submicro-particle anodes in lithium–ion batteries. J Mater Chem A 2:19036–19045
Yoon J, Oh DX, Jo C, Lee J, Hwang DS (2014) Improvement of desolvation and resilience of alginate binders for Si-based anodes in a lithium ion battery by calcium-mediated cross-linking. Phys Chem Chem Phys 16:25628–25635
Kovalenko I, Zdyrko B, Magasinski A, Hertzberg B, Milicev Z, Burtovyy R, Luzinov I, Yushin G (2011) A major constituent of brown algae for use in high-capacity Li–ion batteries. Science 334:75–79
Komaba S, Shimomura K, Yabuuchi N, Ozeki T, Yui H, Konno K (2011) Study on polymer binders for high-capacity SiO negative electrode of Li–ion batteries. J Phys Chem C 115:13487–13495
Chen S, Huang X, Sun B, Zhang J, Liu H, Wang G (2014) Multi-shelled hollow carbon nanospheres for lithium–sulfur batteries with superior performances. J Mater Chem A 2:16199–16207
Wang WG, Wang X, Tian LY, Wang YL, Ye SH (2014) In situ sulfur deposition route to obtain sulfur–carbon composite cathodes for lithium–sulfur batteries. J Mater Chem A 2:4316–4323
Gao M, Li C, Liu N, Chen Y, Wang W, Zhang H, Yu Z, Huang Y (2014) Inhibition on polysulfides dissolve during the discharge–charge by using fish-scale-based porous carbon for lithium–sulfur battery. Electrochim Acta 149:258–263
Noh H, Song J, Park J-K, Kim H-T (2015) A new insight on capacity fading of lithium–sulfur batteries: the effect of Li2S phase structure. J Power Sources 293:329–335
Acknowledgments
Financial support from the Shandong Province Natural Science Foundation of China (ZR2015PE009) is gratefully appreciated. The authors appreciate the support of the “100 Talents” program of Chinese Academy of Sciences and the Qingdao Key Laboratory of Solar Energy Utilization and Energy Storage Technology.
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Zhu, S., Yu, J., Yan, X. et al. Enhanced electrochemical performance from cross-linked polymeric network as binder for Li–S battery cathodes. J Appl Electrochem 46, 725–733 (2016). https://doi.org/10.1007/s10800-016-0957-x
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DOI: https://doi.org/10.1007/s10800-016-0957-x