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Improvement of Bi2Sr2Co2Oy thermoelectric performances by Na doping

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Abstract

Bi2Sr2-xNaxCo2Oy thermoelectric materials with x = 0, 0.025, 0.05, 0.075, 0.10, 0.125, and 0.15 have been prepared by the classical solid state reaction. Microstructure has shown an important grain growth when Na is added, leading to very high bulk densities confirmed through density measurements. These modifications have produced a drastic decrease of electrical resistivity without significant modification of Seebeck coefficient. As a consequence, Power Factor has been increased in all Na-doped samples, reaching the maximum value (0.21 mW/K2.m at 650 °C) for 0.075 Na samples, which is fairly close to the reported for single crystals.

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References

  1. W. Liu, X. Yan, G. Chen, Z. Ren, Nano Energy 1, 42 (2012)

    Article  Google Scholar 

  2. D.M. Rowe, Thermoelectrics Handbook: Macro to Nano, 1st edn. (CRC Press, Boca Raton, 2006), pp. 1-3–1-7

    Google Scholar 

  3. J. Ander Santamaria, J. Alkorta, J. Gil Sevillano, J Mater Res 30, 2593 (2015)

    Article  Google Scholar 

  4. I. Terasaki, Y. Sasago, K. Uchinokura, Phys Rev B 56, 12685 (1997)

    Article  Google Scholar 

  5. A. Maignan, S. Hebert, M. Hervieu, C. Michel, D. Pelloquin, D. Khomskii, J Phys Condens Matter 15, 2711 (2003)

    Article  Google Scholar 

  6. H. Itahara, C. Xia, J. Sugiyama, T. Tani, J Mater Chem 14, 61 (2004)

    Article  Google Scholar 

  7. M.A. Madre, F.M. Costa, N.M. Ferreira, A. Sotelo, M.A. Torres, G. Constantinescu, S. Rasekh, J.C. Diez, J Eur Ceram Soc 33, 1747 (2013)

    Article  Google Scholar 

  8. A.C. Masset, C. Michel, A. Maignan, M. Hervieu, O. Toulemonde, F. Studer, B. Raveau, J. Hejtmanek, Phys Rev B 62, 166 (2000)

    Article  Google Scholar 

  9. A. Sotelo, S. Rasekh, M.A. Madre, E. Guilmeau, S. Marinel, J.C. Diez, J Eur Ceram Soc 31, 1763 (2011)

    Article  Google Scholar 

  10. A. Maignan, D. Pelloquin, S. Hebert, Y. Klein, M. Hervieu, Bol Soc Esp Ceram V 45, 122 (2006)

    Article  Google Scholar 

  11. K. Rubesova, T. Hlasek, V. Jakes, S. Huber, J. Hejtmanek, D. Sedmidubsky, J Eur Ceram Soc 35, 525 (2015)

    Article  Google Scholar 

  12. A. Sotelo, M.A. Torres, G. Constantinescu, S. Rasekh, J.C. Diez, M.A. Madre, J Eur Ceram Soc 32, 3745 (2002)

    Article  Google Scholar 

  13. W. Kobayashi, S. Hebert, H. Muguerra, D. Grebille, D. Pelloquin, A. Maignan, in Proceedings ICT 07: Twenty-sixth international conference on thermoelectrics, ed. By I. Kim (IEEE, Piscataway, 2008), p. 117.

  14. G. Constantinescu, S. Rasekh, M.A. Torres, M.A. Madre, J.C. Diez, A. Sotelo, Scr Mater 68, 75–78 (2013)

    Article  Google Scholar 

  15. N. Sun, S.T. Dong, B.B. Zhang, Y.B. Chen, J. Zhou, S.T. Zhang, Z.B. Gu, S.H. Yao, Y.F. Chen, J Appl Phys 114, 043705 (2013)

    Article  Google Scholar 

  16. W. Shin, N. Murayama, J Mater Res 15, 382 (2000)

    Article  Google Scholar 

  17. A. Sotelo, S. Rasekh, E. Guilmeau, M.A. Madre, M.A. Torres, S. Marinel, J.C. Diez, Mater Res Bull 46, 2537 (2011)

    Article  Google Scholar 

  18. W. Koshibae, K. Tsutsui, S. Maekawa, Phys Rev B 62, 6869 (2000)

    Article  Google Scholar 

  19. M.A. Madre, S. Rasekh, J.C. Diez, A. Sotelo, Mater Lett 64, 2566 (2010)

    Article  Google Scholar 

  20. M. Kato, Y. Goto, K. Umehara, K. Hirota, I. Terasaki, Phys B 378-380, 1062 (2006)

    Article  Google Scholar 

  21. D. Mercurio, J.C. Champarnaud-Mesjard, B. Frit, P. Conflant, J.C. Boivin, T. Vogt, J Solid State Chem 112, 1 (1994)

    Article  Google Scholar 

  22. O. Jankovsky, Z. Sofer, J. Vitek, M. Novacek, T. Hlasek, D. Sedmidubsky, J Eur Ceram Soc 35, 3005 (2015)

    Article  Google Scholar 

  23. M.A. Madre, M.A. Torres, S. Rasekh, J.C. Diez, A. Sotelo, Mater Lett 76, 5 (2012)

    Article  Google Scholar 

  24. K. Rubesova, T. Hlasek, V. Jakes, D. Sedmidubsky, J. Hejtmanek, IOP Conf. Ser. Mater Sci Eng 30, 012004 (2012)

    Google Scholar 

  25. M. Gursul, A. Ekicibil, B. Ozçelik, M.A. Madre, A. Sotelo, J Supercond Nov Magn 28, 1913 (2015)

    Article  Google Scholar 

  26. B. Ozkurt, J Mater Sci Mater Electron 25, 3295 (2014)

    Article  Google Scholar 

  27. Q.L. He, Z. Qin, J. Zhang, F. Gao, X. Hu, H.Z. Song, J Electron Mater 43, 1432 (2014)

    Article  Google Scholar 

  28. M.A. Torres, A. Sotelo, S. Rasekh, I. Serrano, G. Constantinescu, M.A. Madre, J.C. Diez, Bol. Soc. Esp. Ceram. V. 51, 1 (2012)

    Article  Google Scholar 

  29. E. Combe, R. Funahashi, F. Azough, R. Freer, J Mater Res 29, 1376 (2014)

    Article  Google Scholar 

  30. J.C. Diez, S. Rasekh, M.A. Madre, E. Guilmeau, S. Marinel, A. Sotelo, J Electron Mater 39, 1601 (2010)

    Article  Google Scholar 

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Acknowledgements

This work is supported by Research Fund of Cukurova University, Adana, Turkey, under grant contracts no: FBA-2016-6626 and FDK-2016-6105. The Spanish authors thank the Gobierno de Aragón and Fondo Social Europeo (Grupo de Investigacion Consolidado T12) and MINECO-FEDER (MAT2013-46505-C3-1-R) for financial support. Spanish Authors acknowledge the use of Servicio General de Apoyo a la Investigación-SAI, Universidad de Zaragoza.

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Authors and Affiliations

  1. Department of Physics, Faculty of Sciences and Letters, Çukurova University, 01330, Adana, Turkey

    G. Çetin Karakaya & Bekir Özçelik

  2. Department of Material Science and Engineering, Faculty of Engineering, Hakkari University, 30000, Hakkari, Turkey

    O. Nane

  3. Instituto de Ciencia de Materiales de Aragón (CSIC-Universidad de Zaragoza), Ma de Luna, 3, 50018, Zaragoza, Spain

    A. Sotelo, Sh. Rasekh, M. A. Torres & M. A. Madre

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  1. G. Çetin Karakaya
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  2. Bekir Özçelik
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  3. O. Nane
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  4. A. Sotelo
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  5. Sh. Rasekh
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  7. M. A. Madre
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Correspondence to Bekir Özçelik.

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Çetin Karakaya, G., Özçelik, B., Nane, O. et al. Improvement of Bi2Sr2Co2Oy thermoelectric performances by Na doping. J Electroceram 40, 11–15 (2018). https://doi.org/10.1007/s10832-017-0078-x

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  • DOI: https://doi.org/10.1007/s10832-017-0078-x

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