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Multiscale composition modulated Ti–Al composite processed by severe plastic deformation

  • Ultrafinegrained Materials
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Abstract

Using severe plastic deformation processes to consolidate and co-deform powder mixtures to make ultrafine grain composites is a very attractive approach because it offers an almost non-limited room for combinations of phases and composite structures. The aim of this work was to investigate the mechanisms operating at different length scales and leading to multiscale structures, namely co-deformation, fragmentation and mechanical mixing. A Ti–Al composite was processed from a Ti–Al powder mixture prepared by ball milling and subsequently deformed by equal channel angular pressing. Microstructures were characterized at all length scales, down to the nanometre, using optical microscopy, scanning electron microscopy and transmission electron microscopy. It was found that the final structure exhibits unique features at various length scales. Chemical heterogeneities at the micron scale are the result of co-deformation, while at the sub-micron scale they result from the fragmentation and necking of the Ti hard phase. Then, at the nanometer scale, intermixing occurred and nanoscaled intermetallic particles were discovered. This work highlights the possibilities offered by all these mechanisms to design ultrafine grain composite structures for optimized properties.

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References

  1. Hall EO (1951) The deformation and ageing of mild steel: III Discussion of results. Proc Phys Soc B 64:747–753

    Article  Google Scholar 

  2. Petch NJ (1953) The cleavage strength of polycrystals. J Iron Steel Instrum 173:25–28

    Google Scholar 

  3. Orrù R, Licheri R, Locci AM, Cincotti A, Cao G (2009) Consolidation/synthesis of materials by electric current activated/assisted sintering. Mater Sci Eng R 63:127–287

    Article  Google Scholar 

  4. Lu L, Shen Y, Chen X, Qian L, Lu K (2004) Ultrahigh strength and high electrical conductivity in copper. Science 304:422–426

    Article  Google Scholar 

  5. Valiev RZ, Estrin Y, Horita Z, Langdon TG, Zehetbauer MJ, Zhu YT (2006) Producing bulk ultrafine-grained materials by severe plastic deformation. JOM 58(4):33–39

    Article  Google Scholar 

  6. Valiev RZ, Islamgaliev RK, Alexandrov IV (2000) Bulk nanostructured materials from severe plastic deformation. Prog Mater Sci 45:103–189

    Article  Google Scholar 

  7. Sauvage X, Wilde G, Divinsky S, Horita Z, Valiev RZ (2012) Grain boundaries in ultrafine grained materials processed by severe plastic deformation and related phenomena. Mater Sci Eng A 540:1–12

    Article  Google Scholar 

  8. Zhao YH, Liao XZ, Jin Z, Valiev RZ, Zhu YT (2004) Microstructures and mechanical properties of ultrafine grained 7075 Al alloy processed by ECAP and their evolutions during annealing. Acta Mater 34752:4589–4599

    Article  Google Scholar 

  9. Edalati K, Toh S, Iwaoka H, Watanabe M, Horita Z, Kashioka D, Kishida K, Inui H (2012) Ultrahigh strength and high plasticity in TiAl intermetallics with bimodal grain structure and nanotwins. Scr Mater 67:814–817

    Article  Google Scholar 

  10. Sauvage X, Ganeev A, Ivanisenko Y, Enikeev N, Murashkin M, Valiev R (2012) Grain boundary segregation in UFG alloys processed by severe plastic deformation. Adv Eng Mater 14:968–974

    Article  Google Scholar 

  11. Sigl LS, Mataga PA, Dalgleish BJ, McMeeking RM, Evans AG (1988) On the toughening of brittle materials reinforced with a ductile phase. Acta Metall 36:945–953

    Article  Google Scholar 

  12. Embury JD, Fisher RM (1966) The structure and properties of drawn pearlite. Acta Metall 14:147–159

    Article  Google Scholar 

  13. Raabe D, Choi P, Li Y, Kostka A, Sauvage X, Lecouturier F, Hono K, Kirchheim R, Pippan R, Embury D (2010) Metallic composites processed via extreme deformation: towards the limits of strength in bulk materials. MRS Bull 35:982–991

    Article  Google Scholar 

  14. Sauvage X, Jessner P, Vurpillot F, Pippan R (2008) Nanostructure and properties of a Cu–Cr composite processed by severe plastic deformation. Scr Mater 58:1125–1128

    Article  Google Scholar 

  15. Sabirov I, Pippan R (2005) Formation of a W-25 %Cu nanocomposite during high pressure torsion. Scr Mater 52:1293–1298

    Article  Google Scholar 

  16. Tian YZ, Wu SD, Zhang ZF, Figueiredo RB, Gao N, Langdon TG (2011) Microstructural evolution and mechanical properties of a two-phase Cu–Ag alloy processed by high-pressure torsion to ultrahigh strains. Acta Mater 59:2783–2796

    Article  Google Scholar 

  17. Wang J, Kang S-B, Kim H-W (2004) Shear features during equal channel angular pressing of a lamellae eutectic alloy. Mater Sci Eng A 383:356–361

    Article  Google Scholar 

  18. Quelennec X, Menand A, Le Breton JM, Pippan R, Sauvage X (2010) Homogeneous Cu–Fe supersaturated solid solution prepared by SPD, influence of processing parameters and physical mechanisms. Philos Mag 90:1179–1195

    Article  Google Scholar 

  19. Bachmaier A, Hohenwarter A, Pippan R (2009) New procedure to generate stable nanocrystallites by severe plastic deformation. Scr Mater 61:1016–1019

    Article  Google Scholar 

  20. Xia K (2010) Consolidation of particles by severe plastic deformation: mechanism and application in processing bulk ultrafine and nanostructured alloys and composites. Adv Eng Mater 12:724–729

    Article  Google Scholar 

  21. Lui EW, Xu W, Wu X, Xia K (2011) Multiscale two-phase Ti–Al with high strength and plasticity through consolidation of particles by severe plastic deformation. Scr Mater 65:711–714

    Article  Google Scholar 

  22. Bachmaier A, Pippan R (2013) Generation of metallic nanocomposites by severe plastic deformation. Int Mater Rev 58:41–62

    Article  Google Scholar 

  23. Sauvage X, Dinda DG, Wilde G (2007) Non-equilibrium intermixing and phase transformation in severely deformed Al/Ni multilayers. Scr Mater 56:181–184

    Article  Google Scholar 

  24. Vujic D, Li Z, Whang SH (1988) Effect of rapid solidification and alloying addition on lattice distortion and atomic ordering in L1o TiAI alloys and their ternary alloys. Metall Trans A 19A:2445–2455

    Article  Google Scholar 

  25. Massalski TB (1987) Binary alloy phase diagrams. ASM International, Metals Park,294–297

  26. Ramos AS, Vieira MT (2005) Kinetics of the thin films transformation Ti/Al multilayer γ-TiAl. Surf Coat Technol 200:326–329

    Article  Google Scholar 

  27. Gachon J-C, Rogachev AS, Grigoryan HE, Illarionova EV, Kuntz J-J, Kovalev DYu, Nosyrev AN, Sachkova NV, Tsygankov PA (2005) On the mechanism of heterogeneous reaction and phase formation in Ti/Al multilayer nanofilms. Acta Mater 53:1225–1231

    Article  Google Scholar 

  28. Liss K-D, Whitfield RE, Xu W, Buslaps T, Yeoh LA, Wu X, Zhang D, Xia K (2009) In situ synchrotron high-energy X-ray diffraction analysis on phase transformations in Ti–Al alloys processed by equal-channel angular pressing. J Synchrotron Rad 16:825–834

    Article  Google Scholar 

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Sauvage, X., Lui, E.W. & Xia, K. Multiscale composition modulated Ti–Al composite processed by severe plastic deformation. J Mater Sci 49, 6543–6549 (2014). https://doi.org/10.1007/s10853-014-8239-7

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  • DOI: https://doi.org/10.1007/s10853-014-8239-7

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