Abstract
Using trimethyl phosphate and calcium nitrate tetrahydrate as the calcium and phosphorus precursors, respectively, HA films were prepared layer by layer by a sol–gel method. The phase constitution, microstructure and calcium/phosphorus (Ca/P) molar ratio of the sol–gel films were studied by X-ray diffraction (XRD) and electronic probe microanalysis (EPMA). The results show that the sol–gel films have high crystallinity and are composed of HA and CaO phases, and the Ca/P ratio is slightly higher than the theoretical value in HA because of the loss of phosphorous element. Two typical cauliflower-like and lamellar structures were observed in the films. Cauliflower-like structure, which increases the biological reactivity of the implant surface towards natural bone, formed mainly at low drying temperature and high calcining temperature, while the lamellar structure formed when the drying temperature is high (500 °C or above).
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V. NELEA, C. MOROSANU, M. ILIESCU and I. N. MIHAILESCU, Appl. Surf. Sci. 228 (2004) 346
L.-G. YUA, K. A. KHORA, H. LIA and P. CHEANG, Biomaterials 24 (2003) 2695
K. A. KHOR and P. CHEANG, J. Mater. Process. Technol. 63 (1997) 271
Y. C. YANG and E. CHANG, Biomaterials 22 (2001) 1827
Q. BAO, C. CHEN, D. WANG, T. LEI and J. LIU, Mater. Sci. Eng. A429 (2006) 25
Y.-P. LU, G.-Y. XIAO, S.-T. LI, R.-X. SUN and M.-S. LI, Appl. Surf. Sci. 252 (2006) 2412
D.-M. LIU, T. TROCZYNSKIA and W. J. TSENG, Biomaterials 23 (2002) 1227
A. BALAMURUGAN, G. BALOSSIER, S. KANNAN and S. RAJESWARI, Mater. Lett. 60 (2006) 2288
W. XU, W. Y. HU, M. H. LI, Q. Q. MA, P. D. HODGSON and C. E. WEN, Trans. Nonfer. Metals Soc. China 16 (2006) 209
S. ZHANG, Z. XIANTING, W. YONGSHENG, C. KUIA and W. WENJIAN, Surf. Coat. Technol. 200 (2006) 6350
J. HARLE, H.-W. KIM, N. MORDAN, J. C. KNOWLES and V. SALIH, Acta Biomater. 2 (2005) 547
K. CHENG, S. ZHANG, W. WENG and X. ZENG, Surf. Coat. Technol. 198 (2005) 242
W. XU, W. HU, M. LI and C. WEN, Mater. Lett. 60 (2006) 1575
C. M. LOPATIN, V. PIZZICONI, T. L. ALFORD and T. LAURSEN, Thin Solid Films 326 (1998) 227
K. HWANG and Y. LIM, Surf. Coat. Technol. 115 (1999) 172
H.-W. KIM, Y.-H. KOH, L.-H. LI, S. LEE and H.-E. KIM, Biomaterials 25 (2004) 2533
E. MILELLA, F. COSENTINO, A. LICCIULLI and C. MASSARO, Biomaterials 22 (2001) 1425
E. TKALCEC, M. SAUER, R. NONNINGER and H. SCHMIDT, J. Mater. Sci. 36 (2001) 5253
K. CHENG, S. ZHANG and W. WENG, Thin Solid Films 515 (2006) 135
J. ANDERSSON, S. AREVA, B. SPLIETHOFF and M. LINDÉN, Biomaterials 26 (2005) 6827
J. SAWAI, J. Microbiol. Meth. 54 (2003) 177
K. OZEKI, T. YUHTA, Y. FUKUI and H. AOKI, Surf. Coat. Technol. 160 (2002) 54
A. STOCH, W. JASTRZĘBSKI, E. DŁUGOŃ, W. LEJDA, B. TRYBALSKA, G. J. STOCH and A. ADAMCZYK, J. Mol. Struct. 744–747 (2005) 633
I.-S. KIM and P. N. KUMTA, Mat. Sci. Eng. B111 (2004) 232
M.-F. HSIEH, L.-H. PERNG, T.-S. CHIN and H.-G. PERNG, Biomaterials 22 (2001) 2601
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This work is part of a research program financed by Promotional Fund of Scientific Research for Middleaged and Youthful Scientists of Shandong Province (Project No. 02BS056).
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Wang, D., Chen, C., He, T. et al. Hydroxyapatite coating on Ti6Al4V alloy by a sol–gel method. J Mater Sci: Mater Med 19, 2281–2286 (2008). https://doi.org/10.1007/s10856-007-3338-5
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DOI: https://doi.org/10.1007/s10856-007-3338-5