Skip to main content
Log in

Kinetic Fluorimetric Measurement of Trace Resorcinol1 in Phenol Mixtures

  • Original Paper
  • Published:
Journal of Fluorescence Aims and scope Submit manuscript

Abstract

A kinetic spectrofluorimetric method was studied to measure the concentration of trace resorcinol. The proposed method is based on the inhibitory effect of resorcinol on the oxidation of rhodamine B by potassium bromate in the medium of dilute sulfuric acid. The detection limit and linear range of the proposed resorcinol measurement method are 12 μg L−1 and 24∼280 μg L−1, respectively. Relative standard derivations of eleven measurements for 80 μg L−1 and 200 μg L−1 resorcinol solutions are 2.12% and 1.08%, respectively. The trace of resorcinol can be determined directly by the proposed method without any pre-separation process when phenol and many other phenolic compounds are present.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Standard Methods for the Examination of Water and Waster (1985) American public health association. Washington, DC, 16:510

  2. Amankwa LN, Kuhr WG (1991) Indirect fluorescence detection in micellar electrokinetic chromatography. Anal Chem 63:1733–1737

    Article  CAS  Google Scholar 

  3. Lee XP, Kumazawa T, Saito K, Takano M, Hattori H, Seno H, Ishii A, Watanabe-Suzuki K, Suzuki O, Sato K (2002) Determination of cresol isomers and phenol in human body fluids by capillary gas chromatography with cryogenic oven trapping. Anal Lett 35:2093–2103

    Article  CAS  Google Scholar 

  4. Khoschsorur G, Petek W (2000) Rapid determination of benzene metabolites phenol and p-cresol in the urine of petrol stations workers by gas chromatography. Anal Sci 16:589–591

    Article  CAS  Google Scholar 

  5. Bieniek G (1996) Simultaneous determination of phenol, cresol, xylenol isomers and naphthols in urine by capillary gas chromatography. J Chromatography B-Biomed Appl 682:167–172

    Article  CAS  Google Scholar 

  6. de la Guardia M, Khalaf KD, Hasan BA, Morales RA, Carbonell V (1995) In-line, titanium dioxide-catalised, ultraviolet mineralization of toxic aromatic compounds in the waste stream from a flow injection-based resorcinol analyzer. Analyst 120:231–235

    Article  CAS  Google Scholar 

  7. McMahon GP, Kelly MT (1998) Determination of Aspirin and Salicylic Acid in Human Plasma by Column-Switching Liquid Chromatography Using On-Line Solid-Phase Extraction. Anal Chem 70:409–414

    Article  PubMed  CAS  Google Scholar 

  8. Fiehn O, Jekel M (1997) Analysis of phenolic compounds in industrial wastewater with high-performance liquid chromatography and post-column reaction detection. J Chromatogr A 769:189–200

    Article  CAS  Google Scholar 

  9. Kim H, Poh H, Lee H, Chung S, Choi S, Lee K, Han S (2003) Determination of phloroglucinol in human plasma by high-performance liquid chromatography-mass spectrometry. J Chromatogr B 792:307–312

    Article  CAS  Google Scholar 

  10. Mikami E, Goto T, Ohno T, Matsumoto H, Nishida M (2002) Simultaneous analysis of dehydroacetic acid, benzoic acid, sorbic acid and salicylic acid in cosmetic products by solid-phase extraction and high-performance liquid chromatograph. J Pharm, Biomed Anal 28:261–267

    Article  CAS  Google Scholar 

  11. Hua Cui, Jian Zhou, Feng Xu, Chun-Ze Lai, Guo-Hui Wan (2004) Determination of phenolic compounds using high-performance liquid chromatography with Ce4+-Tween 20 chemiluminescence detection. Anal Chim Acta 511:273–279

    Article  CAS  Google Scholar 

  12. Engeberth J, Schmelz EA, Alborn HT, Cardoza YJ, Huang J, Tumlinson JH (2003) Simultaneous quantification of jasmonic acid and salicylic acid in plants by vapor-phase extraction and gas chromatography-chemical ionization-mass spectrometry. Anal Biochem 312:242–250

    Article  Google Scholar 

  13. Lartigue-Mattei C, Lauro-Marty C, Bastide M, Berger JA, Chabard JL, Goutay E, Aiache JM (1993) Determination of phloroglucinol in human plasma by gas chromatography-mass spectrometry. J Chromatogr B 617:140–146

    CAS  Google Scholar 

  14. Glombitza BW, Schmidt PC (1994) Comparison of three new spectrophotometric methods for simultaneous determination of aspirin and salicylic acid in tablets without separation of pharmaceutical excipients. J Pharm Sci 83:751

    Article  PubMed  CAS  Google Scholar 

  15. Parham H, Pourreza N, Cheraghi S (1999) Kinetic spectrophotometric determination of trace amounts of resorcinol based on its inhibitory effect on the formaldehyde catalysed reaction between bromate and neutral red. Anal Lett 32:1917–1926

    CAS  Google Scholar 

  16. Afkhami A, Afshar-E-Asl A (2000) Kinetic-spectophotometric determination of hydrazine by the inhibition of the bromate–hydrochloric acid reaction. Anal Chim Acta 419:101–106

    Article  CAS  Google Scholar 

  17. Goulden PD (1978) Environmental pollution analysis. Heyden and S Ltd. (USA). p 190

  18. Zhi-Yong Huang, Guo-Shu Chen, Zai-Jiang Peng (1998) Inhibitory kinetic-spectrophotometric determination of trace resorcinol. Chinese J Anal Chem 11:1298–1302

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jing Fan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fan, J., Zhang, T., Sun, J. et al. Kinetic Fluorimetric Measurement of Trace Resorcinol1 in Phenol Mixtures. J Fluoresc 17, 113–118 (2007). https://doi.org/10.1007/s10895-006-0128-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10895-006-0128-2

Keywords

Navigation