Abstract
A novel metal sulfide NaTS-2 was prepared using a simple one-step hydrothermal method to remove strontium ions from the simulated radioactive wastewater, in which metal tin was replaced by tin salts to reduce the cost of the raw materials. NaTS-2 has a layered structure with an approximate molar ratio of Na:Sn:S of 1.94:2.87:7. NaTS-2 could rapidly remove Sr2+ with a removal efficiency of 99.3% ± 0.23% within 1 min and at an equilibrium of 60 min, followed by the pseudo-second-order model and Langmuir model with a maximum adsorption capacity of 88.9 ± 0.81 mg/g at 298 K. NaTS-2 exhibited an outstanding affinity for Sr2+ (Kd ≥ (3.0 ± 0.10) × 105 mL/g) over a broad pH range of 3–11, also displayed significant affinity (Kd ≥ (1.0 ± 0.15) × 105 mL/g) and excellent removal efficiency (≥ 98.5% ± 0.48%) for typical activated corrosion products (Co2+, Mn2+ and Ni2+). NaTS-2 is a promising adsorbent in the field of radioactive wastewater treatment.
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Acknowledgements
The authors are grateful for the financial support from the Major Science and Technology Program for Water Pollution Control and Treatment of China (2015ZX07406006), and Foundation of Tianjin University (2202).
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Guo, J., Wang, Z., Zhang, G. et al. Rapid and effective removal of strontium ions from aqueous solutions by a novel layered metal sulfide NaTS-2. J Radioanal Nucl Chem 332, 2367–2378 (2023). https://doi.org/10.1007/s10967-023-08850-3
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DOI: https://doi.org/10.1007/s10967-023-08850-3