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Loading insoluble sulfides in mesoporous oxide films from precursors in solution

  • Original Paper: Sol-gel and hybrid materials with surface modification for applications
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Abstract

E-waste from the electric and electronics industry is an emerging threat due to the pollution caused by hazardous cations. Immobilization and confinement of these cations as nanoparticles (NPs) in porous materials provide a strategy for the recovery and recycling of hazardous cations. Therefore, we propose the use of mesoporous oxides (MPO) films where the pores act as nanoreactors for the precipitation of metal sulfides (MS) to achieve a process in which dissolved cations are removed and at the same time form a nanostructure to serve as a basis for future designs. In this work, we present a detailed study of the formation of metal sulfides (MS - M = Cd, Zn, Co, Ni) NPs controlling the NP growth in the pores of the MPO by a successive ionic layer adsorption and reaction (SILAR) process. By varying diverse variables of interest such as pH, matrix composition (SiO2, TiO2, ZrO2), isoelectric point (IP) of the inorganic pore surface by organic functionalizers, we show that precipitation is comparable for the different metal sulfides where transport in the mesoporosity and the electrical charge of the surface, as well as the solvent, control the physicochemical response of the system. Understanding the role of each variable allows the limitations of loading MPOs to be identified and the pore filling to be optimized, although ion transport limitations in aqueous solutions lead to inhomogeneous distributions. Through a thorough characterization study (SEM, TEM, UVVIS, EEP, XRR, XPS), it was concluded that MPO thin films are useful platforms for the efficient removal of cations dissolved in water and even in alcohols.

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Highlights

  • Diverse metal sulfides nanoparticles were confined in the pores of mesoporous thin films.

  • Successive ionic layer adsorption and reaction (SILAR) gives precipitation in mesopores.

  • Progressive pore filling and composite structure were exhaustively characterized by complementary techniques.

  • Pore oxide surface, functionalization and geometry affect filling, clogging, and particle formation.

  • Heterogeneous nucleation is controlled by the cation interaction with the oxide surface.

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Acknowledgements

This work was supported by Universidad de Buenos Aires (UBACyT 20020190200245BA & 20020190100299BA) and CONICET funding PIP 11220170100289CO. ABTLus is kindly acknowledged for permitting access to LNLS synchrotron (project XRD1-15366). MCM, SAB and MLMR are members of CONICET. Ezequiel Ortiz is kindly acknowledged for 3D standalone pore schemes. We thank reviewers and specially the editor for their valuable comments on the manuscript.

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Authors and Affiliations

  1. Instituto de Química Física de los Materiales, Medio Ambiente y Energía, (INQUIMAE) CONICET Universidad de Buenos Aires, Buenos Aires, Argentina

    Diego Onna, María Luz Martínez Ricci & Sara A. Bilmes

  2. Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina

    Diego Onna, María Claudia Marchi & Sara A. Bilmes

  3. Centro de Microscopías Avanzadas (CMA), Facultad de Ciencias Exactas y Naturales and Instituto de Física de Buenos Aires (IFIBA) CONICET, Buenos Aires, Argentina

    María Claudia Marchi

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  1. Diego Onna
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  2. María Claudia Marchi
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  3. María Luz Martínez Ricci
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  4. Sara A. Bilmes
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Onna, D., Marchi, M.C., Martínez Ricci, M.L. et al. Loading insoluble sulfides in mesoporous oxide films from precursors in solution. J Sol-Gel Sci Technol 102, 264–278 (2022). https://doi.org/10.1007/s10971-021-05718-4

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