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Structural, thermal decomposition and luminescent studies on gel grown crystals of poly[tetraaquadinicotinatostrontium(II)] containing ‘χ’-shaped hydrophobic channels

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Abstract

Single crystals of the polymeric title complex tetraaquadinicotinatostrontium (SPYC) were successfully grown by a simple and efficient method—the gel encapsulation technique. Sodium metasilicate was used as the gel medium for this purpose. The crystal structure of the complex indicates that it belongs to triclinic system with space group \(P\overline{1}\). The packing diagram of the complex shows uniformly arranged ‘χ’-shaped hydrophobic channels. The thermal decomposition of the crystals have been studied by thermogravimetric analysis at four different heating rates and kinetic parameters including apparent activation energy (Ea), and pre-exponential factor (log A) were calculated by Kissinger, Ozawa and Flynn–Wall–Ozawa methods. Analytical techniques including FT-IR, CHN, powder and single-crystal X-ray diffraction were also carried out to characterize the grown crystals. The solid-state luminescent properties of free ligand and complex were also investigated at room temperature.

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Acknowledgements

RD is thankful to the University of Kerala, Trivandrum, India, for the University Research Fellowship. We sincerely thank Dr. R. Rajeev, Head, Analytical and Spectroscopy Division, VSSC, Trivandrum, Kerala, for his help and valuable suggestions on thermal decomposition studies. We are also grateful to Dr. Shibu M. Eapen, SAIF, CUSAT, Kochi, India, for single-crystal X-ray diffraction measurements and Dr. A. Santhosh Kumar, School of Pure and Applied Physics, M. G University, Kottayam, India, for luminescent studies.

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Authors and Affiliations

  1. Department of Chemistry, Mahatma Gandhi College, Thiruvananthapuram, Kerala, 695 004, India

    Drisya R., Soumyamol U. S., Satheesh Chandran P. R. & Sudarsanakumar M. R.

  2. Department of Chemistry, School of Physical Sciences, Central University of Kerala, Riverside Transit Campus, Padenakad, Nileshwar, Kerala, 671 314, India

    Prathapachandra Kurup M. R.

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  1. Drisya R.
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Correspondence to Sudarsanakumar M. R..

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Drisya, R., Soumyamol, U.S., Satheesh Chandran, P.R. et al. Structural, thermal decomposition and luminescent studies on gel grown crystals of poly[tetraaquadinicotinatostrontium(II)] containing ‘χ’-shaped hydrophobic channels. J Therm Anal Calorim 134, 1987–1999 (2018). https://doi.org/10.1007/s10973-018-7868-5

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