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Fe3O4@THAM-piperazine: a novel and highly reusable nanocatalyst for one-pot synthesis of 1,8-dioxo-octahydro-xanthenes and benzopyrans

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Abstract

A novel magnetically heterogeneous nanocatalyst has been successfully synthesized via the immobilization of piperazine on tris (hydroxymethyl) aminomethane-coated Fe3O4 magnetic nanoparticles. The described catalyst was fully characterized by various techniques such as FT-IR, EDS, DTG/TGA, XRD, TEM, SEM, and VSM analyses. The catalytic efficacy of Fe3O4@THAM-piperazine has investigated for one-pot synthesis of tetrahydrobenzo[b]pyran and 1,8-dioxo-octahydro-xanthene derivatives. Notable features of this user-friendly catalytic system include high yields, high catalytic activity, simple operation, non-toxicity, and easy work-up. Also, the new nanocatalyst could be easily recovered and reused for six times without significant loss of activity.

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The authors are grateful to the research affairs of the University of Sistan and Baluchestan.

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Correspondence to Nourallah Hazeri.

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Faroughi Niya, H., Hazeri, N., Fatahpour, M. et al. Fe3O4@THAM-piperazine: a novel and highly reusable nanocatalyst for one-pot synthesis of 1,8-dioxo-octahydro-xanthenes and benzopyrans. Res Chem Intermed 46, 3651–3666 (2020). https://doi.org/10.1007/s11164-020-04166-z

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  • DOI: https://doi.org/10.1007/s11164-020-04166-z

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