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Green and catalyst-free synthesis of aminoanthraquinone derivatives in solvent-free conditions

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Abstract

In this study, new derivatives of aminoanthraquinone have been synthesized via one-pot three-component condensation reaction of 1- and 2-amino anthraquinones, triethyl orthoformate and CH-acid compounds without using any solvent or catalyst in mild temperature (50 °C). This simple and efficient method yields the desired products in short reaction time (14–50 min) and good to excellent yields (85–96%). Moreover, chemical structures of synthesized products have been entirely confirmed by FT-IR, 1H and 13CNMR and mass spectroscopy and melting points.

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Acknowledgements

We wish to express our thanks to the Research Council of the University of Sistan and Baluchestan for the financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, P.O. Box: 98135-674, Zahedan, Iran

    Arezoo Sardashti-Birjandi, Ebrahim Mollashahi & Malek Taher Maghsoodlou

  2. Young Researchers and Elite Club, Yazd Branch, Islamic Azad University, Yazd, Iran

    Afshin Yazdani-Elah-Abadi

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  1. Arezoo Sardashti-Birjandi
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  2. Ebrahim Mollashahi
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  3. Malek Taher Maghsoodlou
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  4. Afshin Yazdani-Elah-Abadi
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Correspondence to Ebrahim Mollashahi.

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Sardashti-Birjandi, A., Mollashahi, E., Maghsoodlou, M.T. et al. Green and catalyst-free synthesis of aminoanthraquinone derivatives in solvent-free conditions. Res Chem Intermed 47, 3597–3608 (2021). https://doi.org/10.1007/s11164-021-04485-9

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