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Cellulose Schiff base-supported Pd(II): An efficient heterogeneous catalyst for Suzuki Miyaura cross-coupling

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Abstract

Cellulose-supported Schiff base Pd(II) complex [(Cell-Sc-Pd(II))] has been designed and synthesized by multistep approach. (Cell-Sc-Pd(II)) was characterized by techniques, viz. FT-IR, XRD, XPS, EDS, FE-SEM and TGA. Catalytic activity of (Cell-Sc-Pd(II)) is explored for Suzuki Miyaura cross-coupling of phenyl boronic acid and aryl halides. Special features of present method are high TONs and TOFs, low catalyst loading (0.0016 mol %), reusability of the catalyst at least for five times and synthesis of novel biphenyl derivatives of xanthenes.

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Acknowledgements

One of the authors, Pharande P. S., is grateful to the Council of Scientific and Industrial Research (CSIR), New Delhi, Government of India, for the award of the Junior Research Fellowship (File no. 09/816(0044)/2019-EMR-I).

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  1. Department of Chemistry, Shivaji University, Kolhapur, Maharashtra, India

    P. S. Pharande, G. S. Rashinkar & D. M. Pore

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  1. P. S. Pharande
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Pharande, P.S., Rashinkar, G.S. & Pore, D.M. Cellulose Schiff base-supported Pd(II): An efficient heterogeneous catalyst for Suzuki Miyaura cross-coupling. Res Chem Intermed 47, 4457–4476 (2021). https://doi.org/10.1007/s11164-021-04528-1

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