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Synthesis of Aromatic Carboxylic Acids by Carbonylation of Aryl Halides in the Presence of Epoxide-Modified Cobalt Carbonyls as Catalysts

  • Applied Electrochemistry and Corrosion Protection of Metals
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Abstract

A new procedure was developed for synthesis of aromatic and heteroaromatic acids and their derivatives (esters, salts) by carbonylation of the corresponding aryl halides. The acids are selectively formed in a high yield under very mild conditions. Highly active catalytic systems, base-containing alcoholic solutions of cobalt carbonyl modified with epoxides, were used to activate aryl halides.

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Translated from Zhurnal Prikladnoi Khimii, Vol. 78, No. 11, 2005, pp. 1875–1880.

Original Russian Text Copyright © 2005 by Boyarskii, Zhesko, Lanina.

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Boyarskii, V.P., Zhesko, T.E. & Lanina, S.A. Synthesis of Aromatic Carboxylic Acids by Carbonylation of Aryl Halides in the Presence of Epoxide-Modified Cobalt Carbonyls as Catalysts. Russ J Appl Chem 78, 1844–1848 (2005). https://doi.org/10.1007/s11167-005-0619-y

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  • DOI: https://doi.org/10.1007/s11167-005-0619-y

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