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Synthesis of 3-acyl-5-nitroisoxazoles on the base of geminal trinitro- and chlorodinitro-substituted pentan-2-one or 2-oximino-1-phenylbutan-1-one

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Abstract

3-Acyl-5-nitroisoxazoles were synthesized by heating 5,5,5-trinitropentan-2-one with LiCl in DMF at 100 °C as well as by heating oximino derivatives of 5,5,5-trinitro-, 5-chloro-5,5-dinitropentan-2-one or 4,4,4-trinitro- and 4-chloro-4,4-dinitro-1-phenylbutan-1-one in organic solvents.

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Authors and Affiliations

  1. State Scientific Research Institute “Krislall”, 6 ul. Zelenaya, 606007, Dzerzhinsk, Nizhny Novgorod Region, Russian Federation

    G. Kh. Khisamutdinov

  2. Scientific Research Institute of Chemical Products, 1 ul. Svetlaya, 42002, Kazan, Russian Federation

    N. M. Lyapin

  3. Kazan State Technological University, 68 ul. K. Marksa, 420015, Kazan, Russian Federation

    V. G. Nikitin

  4. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    V. I. Slovetskii & A. A. Fainzil’berg

Authors
  1. G. Kh. Khisamutdinov
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  2. N. M. Lyapin
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  3. V. G. Nikitin
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  4. V. I. Slovetskii
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  5. A. A. Fainzil’berg
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Correspondence to G. Kh. Khisamutdinov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2113—2116, October, 2009.

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Khisamutdinov, G.K., Lyapin, N.M., Nikitin, V.G. et al. Synthesis of 3-acyl-5-nitroisoxazoles on the base of geminal trinitro- and chlorodinitro-substituted pentan-2-one or 2-oximino-1-phenylbutan-1-one. Russ Chem Bull 58, 2178–2181 (2009). https://doi.org/10.1007/s11172-009-0299-5

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  • DOI: https://doi.org/10.1007/s11172-009-0299-5

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