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Bromination of alkenols with the H2O2—LiBr—CeIII and H2O2—LiBr—CeIV systems

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Abstract

Reactions of alkenols with H2O2—LiBr—Ce(NO3)3·6H2O or H2O2—LiBr—Ce(NH4)2(NO3)6 system led to bromination of the double bond to yield vicinal dibromoalkanols. The reaction proceeded highly selectively, no oxidation of the hydroxyl group virtually occurred.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    G. I. Nikishin, L. L. Sokova & N. I. Kapustina

Authors
  1. G. I. Nikishin
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  2. L. L. Sokova
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  3. N. I. Kapustina
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Correspondence to N. I. Kapustina.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 456–460, February, 2012.

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Nikishin, G.I., Sokova, L.L. & Kapustina, N.I. Bromination of alkenols with the H2O2—LiBr—CeIII and H2O2—LiBr—CeIV systems. Russ Chem Bull 61, 459–463 (2012). https://doi.org/10.1007/s11172-012-0064-z

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  • DOI: https://doi.org/10.1007/s11172-012-0064-z

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