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A palladacyclic azobenzene derivative as a catalyst for carbon-carbon bond formation reactions

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Abstract

A bis-chelated palladacycle in which the Pd atom is [(C, N)(C, N)]-tetracoordinated to two azobenzene ligands proved to be a moderately active catalyst for the Suzuki and Heck reactions. A voltammetric study revealed that the two-electron oxidation of this complex is accounted for by the irreversible PdII/PdIV transition.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    L. A. Bulygina, N. S. Khrushcheva, S. M. Peregudova & V. I. Sokolov

Authors
  1. L. A. Bulygina
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  2. N. S. Khrushcheva
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  3. S. M. Peregudova
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  4. V. I. Sokolov
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Correspondence to L. A. Bulygina.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1980–1982, October, 2012.

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Bulygina, L.A., Khrushcheva, N.S., Peregudova, S.M. et al. A palladacyclic azobenzene derivative as a catalyst for carbon-carbon bond formation reactions. Russ Chem Bull 61, 1998–2000 (2012). https://doi.org/10.1007/s11172-012-0277-1

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  • DOI: https://doi.org/10.1007/s11172-012-0277-1

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