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Synthesis of 4-(dibromomethyl)benzenecarbaldehyde and its reactions with N- and O-nucleophiles

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Abstract

4-(Dibromomethyl)benzenecarbaldehyde was first synthesized and its preparation method jointly with terephthalic aldehyde was developed. Its reactions with O- and N-nucleophiles were studied: the reaction of this aldehyde with trialkyl orthoformates results in the formation of acetals while reacting with primary amines it forms imines, including those containing an additional acetal group.

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Authors and Affiliations

  1. Kazan National Research Technological University, 68 ul. Karla Marksa, 420015, Kazan, Russian Federation

    M. B. Gazizov, S. Yu. Ivanova, R. F. Karimova, L. R. Bagauva, K. S. Gazizova & A. A. Karimova

Authors
  1. M. B. Gazizov
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  2. S. Yu. Ivanova
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  3. R. F. Karimova
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  4. L. R. Bagauva
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  5. K. S. Gazizova
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  6. A. A. Karimova
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Corresponding author

Correspondence to M. B. Gazizov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0191—0194, January, 2016.

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Gazizov, M.B., Ivanova, S.Y., Karimova, R.F. et al. Synthesis of 4-(dibromomethyl)benzenecarbaldehyde and its reactions with N- and O-nucleophiles. Russ Chem Bull 65, 191–194 (2016). https://doi.org/10.1007/s11172-016-1282-6

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  • DOI: https://doi.org/10.1007/s11172-016-1282-6

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