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Highly selective catalysts for liquid-phase hydrogenation of substituted alkynes based on Pd—Cu bimetallic nanoparticles

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Abstract

Catalytic properties of Pd—Cu bimetallic catalysts supported on SiO2 and Al2O3 were studied in a model reaction of selective hydrogenation of diphenylacetylene. Application of PdCu2(AcO)6 heterobimetallic acetate complex as a precursor made it possible to obtain homogeneous Pd—Cu bimetallic nanoparticles. This result was supported by the data of IR spectroscopy of adsorbed CO. The Pd-Cu catalysts showed considerably higher selectivity than monometallic samples. Moreover, the introduction of copper decreases the hydrogenation rate of diphenylethylene (DPE) to diphenylethane. As a result, the maximum yield of the target product, DPE, increased from 78 to 93% in the presence of Pd—Cu catalysts.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    I. S. Mashkovsky, P. V. Markov, G. O. Bragina, O. P. Tkachenko & A. Yu. Stakheev

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    I. A. Yakushev, N. Yu. Kozitsyna & M. N. Vargaftik

Authors
  1. I. S. Mashkovsky
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  2. P. V. Markov
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  3. G. O. Bragina
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  4. O. P. Tkachenko
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  5. I. A. Yakushev
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  6. N. Yu. Kozitsyna
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  7. M. N. Vargaftik
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  8. A. Yu. Stakheev
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Correspondence to A. Yu. Stakheev.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0425—0431, February, 2016.

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Mashkovsky, I.S., Markov, P.V., Bragina, G.O. et al. Highly selective catalysts for liquid-phase hydrogenation of substituted alkynes based on Pd—Cu bimetallic nanoparticles. Russ Chem Bull 65, 425–431 (2016). https://doi.org/10.1007/s11172-016-1316-0

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  • DOI: https://doi.org/10.1007/s11172-016-1316-0

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