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Three metal organic frameworks based on mixed ligands: synthesis, crystal structures and luminescent sensing of nitro explosives

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Abstract

Three new metal organic frameworks [Zn(bipa)(suc)]n (1), [Ni(bipa)(suc)(H2O)2]n (2) and [Co(bipa)1.5(oip)(H2O)]n (3) (bipa = 2,5-bis(1-imidazole)pyrazine), H2suc = succinic acid, H2oip = 5-hydroxy isophthalic acid) have been synthesized by solvothermal method. They were then characterized by single crystal X-ray diffraction, elemental analysis, infrared spectrum and thermogravimetric analysis. Structural analyses showed that MOFs 1 and 3 exhibited a 3D supramolecular network, while MOF 2 presented a 2D layered structure and was further assembled to a 3D architecture via intermolecular O–H···O hydrogen bond. Moreover, the luminescence sensing of MOF 1 toward nitro explosives was investigated, owing to its excellent chemical stability and luminescence properties. MOF 1 showed remarkable fluorescence quenching toward TNP with a high Ksv value of 6.48 × 104 M−1 and a low limit of detection of 1.4 × 10−5 M. Also, the luminescent sensing mechanism of MOF 1 was investigated.

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Acknowledgements

This project is supported by the Natural Science Foundation of Inner Mongolia (No. 2021LHMS02008), the Graduate Research Innovation Fund of Inner Mongolia Normal University (CXJJS20109) and collaborative innovation center for water environmental security of Inner Mongolia Autonomous Region (XTCX003).

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Authors and Affiliations

  1. Inner Mongolia Key Laboratory of Environmental Chemistry, College of Chemistry and Environment Science, Inner Mongolia Normal University, Hohhot, 010022, China

    Shuang-Shuang Ge, Yan-Hong Zhang, Xiao-Qing Yang & Xian-Gui Mu

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  1. Shuang-Shuang Ge
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  2. Yan-Hong Zhang
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  3. Xiao-Qing Yang
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  4. Xian-Gui Mu
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Contributions

Shuang-Shuang Ge: Software, Validation, Writing - Original Draft. Yan-Hong Zhang: Supervision, Funding acquisition, Methodology, Writing - review & editing Xiao-Qing Yang: Data curation, Investigation Xian-Gui Mu: Performed the experiment, Project administration. All authors reviewed the manuscript

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Correspondence to Yan-Hong Zhang.

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Ge, SS., Zhang, YH., Yang, XQ. et al. Three metal organic frameworks based on mixed ligands: synthesis, crystal structures and luminescent sensing of nitro explosives. Transit Met Chem 48, 37–45 (2023). https://doi.org/10.1007/s11243-023-00521-2

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  • DOI: https://doi.org/10.1007/s11243-023-00521-2

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