Abstract
Heterostructures of metal-organic frameworks (MOFs) and metal oxides have currently been explored for their application in heterogeneous photocatalysis for wastewater remediation. We have developed two new heterostructures fabricated by integration of the [Zn(apca)2]n (Zn–MOF) and [CdCl2(apca)]n (Cd–MOF) over the hexagonal-faced surface of ZnO synthesized by template-assisted method and abbreviated as Zn/Cd–MOF@ZnO. The as-synthesized heterostructures were characterized by employing morphological (FE–SEM), thermal (TGA), and spectral techniques (FT–IR, UV–Vis, XPS, and PXRD). Their performance for the degradation of hazardous industrial dyes (methylene blue (MB), malachite green (MG), and methyl violet (MV)) has been explored. The response in terms of photodegradation efficacy, (89.4%, 90%) MB, (90.7%, 94.5%) MG, and (90.1%, 92.5%) MV was recorded in the presence of Zn–MOF@ZnO and Cd–MOF@ZnO heterostructures, respectively, at optimal conditions (pH–7, catalyst dose–0.6 g/L, and dye concentration–5 mg/L). The rate constant values for Zn–MOF@ZnO and Cd–MOF@ZnO heterostructures are (0.0247 min−1, 0.0315 min−1) MB, (0.0312 min−1, 0.0359 min−1) MG, and (0.0278 min−1, 0.0372 min−1) MV, respectively. These heterostructures are found to be promising photocatalysts as compared to pristine metal oxides owing to their synergistic effect. Moreover, the heterostructures have low band gap energy and high surface area which results in offering more active sites for carrying out photocatalytic reactions and enhancing the efficiency of catalysts. Furthermore, the fabricated photocatalysts demonstrate excellent stability and recyclability over five experimental cycles.
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Wang C-C, Li J-R, Lv X-L, Zhang Y-Q, Guo G (2014) Energ. Environ Sci 7:2831–2867. https://doi.org/10.1039/C4EE01299B
Bansal P, Kaur, D (2020) Sud Chapter 7
Gleick PH (2000) Water Int 25:127–138. https://doi.org/10.1080/02508060008686804
Wu Z, Yuan X-Z, Zhang Z, Wang H, Jiang L, Zeng G (2016) ChemCatChem 9:41–64. https://doi.org/10.1002/cctc.201600808
Deshphande SD (2001) Ind J Fibre Text Res 26:136–142
Lin C, Qiao Z, Zhang J, Tang J, Zhang Z, Guo Z (2019) ES Energy Environ 4:27–33
Chen J, Wang X, Huang Y, Lv S, Cao X, Yun J, Cao D (2018). Eng Sci. https://doi.org/10.30919/es8d666
Wei H, Ma J, Shi Y, Cui D, Liu M, Lu N, Wang N, Wu T, Wujcik EK, Guo Z (2018) ES Mater Manuf 2:28–34
Yang X, You F, Zhao Y, Bai Y, Shao L (2018) ES Energy Environ 1:106–113
Sun M, Yuan L, Yang X, Shao L (2020) ES Mater Manuf 9:40–47
Burgaz E, Erciyes A, Andac M, Andac O (2019) Inorg Chim Acta 485:118–124. https://doi.org/10.1016/j.ica.2018.10.014
Xiao H, Zhang W, Yao Q, Huang L, Chen L, Boury B, Chen Z (2019) Appl Catal B 244:719–731. https://doi.org/10.1016/j.apcatb.2018.11.026
Lu C-M, Liu J, Xiao K, Harris AT (2010) Chem Eng J 156:465–470. https://doi.org/10.1016/j.cej.2009.10.067
Sud D, Kaur G (2021) Polyhedron 193:114897. https://doi.org/10.1016/j.poly.2020.114897
Yang J, Hou W, Pan R, Zhou M, Zhang S, Zhang Y (2022) J Alloy Compd 897:163187. https://doi.org/10.1016/j.jallcom.2021.163187
Kaur G, Anthwal A, Kandwal P, Sud D (2023) Inorganica Chim Acta 545:121248. https://doi.org/10.1016/j.ica.2022.121248
Abazari R, Ataei F, Morsali A, Slawin AMZ, Warren CLC, Appl ACS (2019) Mater Interfaces 11:45442–45454. https://doi.org/10.1021/acsami.9b16473
Goh SH, Lau HS, Yong WF (2022) Small 18:2107536. https://doi.org/10.1002/smll.202107536
Qiu T, Liang Z, Guo W, Tabassum H, Gao S, Zou R (2020) ACS Energy Lett 5:520–532. https://doi.org/10.1021/acsenergylett.9b02625
Tan X, Liu J, Huang Q, Wu Y, Lin X, Zeb A, Yuan Z, Xu X, Luo Y (2022) J Alloy Compd 895:162569. https://doi.org/10.1016/j.jallcom.2021.162569
Wanigarathna DKJA, Gao J, Liu B (2020) Mater Adv 1:310–320. https://doi.org/10.1039/D0MA00083C
Liang Y, Zeng Z, Yang J, Yang G, Han Y (2021) Coll Surf A 624:126796. https://doi.org/10.1016/j.colsurfa.2021.126796
Hu L, Mao D, Yang L, Zhu MS, Fei ZH, Sun SX, Fang D (2022) Environ Res 203:111874. https://doi.org/10.1016/j.envres.2021.111874
Hassanpour M, Hojaghan HS, Niasari MS (2017) Mol Liq 229:293–299. https://doi.org/10.1016/j.molliq.2016.12.090
Ajabshir SZ, Derazkola SM, Niasari MS (2018) Ultrason Sonochem 42:171–182. https://doi.org/10.1016/j.ultsonch.2017.11.026
Ajabshir SZ, Niasari MS (2019) Compos Part B 174:106930. https://doi.org/10.1016/j.compositesb.2019.106930
Mohatari F, Mozdianfard MR, Niasari MS (2015) Saf Environ Prot 93:282–292. https://doi.org/10.1016/j.psep.2014.06.006
Monsef R, Arani MG, Niasari MS, Appl ACS (2021) Energy Mater 4:680–695. https://doi.org/10.1021/acsaem.0c02557
Ajabshir S, Morassaei MS, Amiri O, Niasari MS, Foong LK (2020) Foong ceram. Int 46:17186–17196. https://doi.org/10.1016/j.ceramint.2020.03.014
Amiri M, Salavati-Niasari M, Pardakhty A, Ahmadi M, Akbari A (2017) Caffeine: a novel green precursor for synthesis of magnetic CoFe2O4 nanoparticles and pH-sensitive magnetic alginate beads for drug delivery. Mater Sci Eng C 76:1085–1093. https://doi.org/10.1016/j.msec.2017.03.208
Monsef R, Niasari MS (2021) Biosens Bioelectron 178:113017. https://doi.org/10.1016/j.bios.2021.113017
Anwer S, Anjum DH, Luo S, Abbas Y, Li B, Iqbal S, Liao K (2021) Chem Eng J 406:126827. https://doi.org/10.1016/j.cej.2020.126827
Irfan RM, Tahir MH, Maqsood M, Lin Y, Bashir T, Iqbal S, Zhao J, Gao L, Haroon M (2020) J Catal 390:196–205. https://doi.org/10.1016/j.jcat.2020.07.034
Ikram M, Haider A, Imran M, Haider J, Naz S, Ul-Hamid A, Shahzadi A, Ghazanfar K, Nabgan W (2023) Int J Biol Macromol 230:123190. https://doi.org/10.1016/j.ijbiomac.2023.123190
Wei T, Niu B, Zhao G (2020) ACS Appl Mater Interfaces 12:39273–39281
Xia G, Zheng Y, Sun Z, Xia S, Ni Z, Yao J (2022) Environ Sci Pollut Res 29:39441–39450. https://doi.org/10.1007/s11356-022-18989-3
Xu P, Ding C, Li Z, Yu R, Cui H, Gao S (2023) Chemosphere 319:137995. https://doi.org/10.1016/j.chemosphere.2023.137995
Patel RV, Yadav A (2022) J Mol Struct 1252:132128. https://doi.org/10.1016/j.molstruc.2021.132128
Iqbal S, Bahadur A, Javed M, Hakami O, Irfan RM, Ahmad Z, Alobaid A, Al-Anazy MM, Baghdadi HB, Abd-Rabboh HSM, Al-Muhimeed TI, Liu G, Nawaz M (2021) J Mater Sci Eng B 272:115320. https://doi.org/10.1016/j.mseb.2021.115320
Goktas S, Goktas A (2021) J Alloy Compd 863:158734. https://doi.org/10.1016/j.jallcom.2021.158734
Sher M, Javed M, Shahid S, Iqbal S, Qamar MA, Bahadur A, Qayyum MA (2021) RSC Adv 11:2025–2039. https://doi.org/10.1039/D0RA08573A
Chinnathambi A (2022) J Alloy Compd 890:161742. https://doi.org/10.1016/j.jallcom.2021.161742
Trindade LG, Borba KMN, Trench AB, Zanchet L, Teodoro V, Pontes FML, Longo E, Mazzo TM (2021) J Solid State Chem 293:121794. https://doi.org/10.1016/j.jssc.2020.121794
Samy M, Ibrahim MG, Alalm MG, Fujii M (2020) Sep Purif Technol 249:117173. https://doi.org/10.1016/j.seppur.2020.117173
Wang X, Cao Z, Du B, Zhang Y, Zhang R (2020) Compos Part B 183:107685. https://doi.org/10.1016/j.compositesb.2019.107685
Gupta NK, Bae J, Kim S, Kim KS (2021) Chemosphere 274:129789. https://doi.org/10.1016/j.chemosphere.2021.129789
Mahmoodi NM, Oveisi M, Taghizadeh A (2019) J Hazard Mater 368:746–759. https://doi.org/10.1016/j.jhazmat.2019.01.107
Kumar G, Masram DT (2021) ACS Omega 6:9587–9599. https://doi.org/10.1021/acsomega.1c00143
Kaur A, Bajaj B, Kaushik A, Saini A, Sud D (2002) Mater Sci Eng B 286:116005. https://doi.org/10.1016/j.mseb.2022.116005
Kaur A, Bajaj B, Sud D (2022) J Iran Chem Soc 19(11):4473–4489. https://doi.org/10.1007/s13738-022-02616-6
Kaur G, Komal PK, Sud D (2023) J Solid State Chem 319:123833. https://doi.org/10.1016/j.jssc.2022.123833
Kaur A, Mehta VS, Kaur G, Sud D (2023). Environ Sci Pollut Res. https://doi.org/10.1007/s11356-023-25234-y
Modwi A, Taha KK, Khezami L, Al-Ayed AS, Al-Duaij OK, Khairy M, Bououdina M (2020) J Inorg Organomet Polym Mater 30:2633–2644. https://doi.org/10.1007/s10904-019-01425-4
Chemingui H, Mzali JC, Missaoui T, Konyar M, Smiri M, Yatmaz HC, Hafiane A (2021) Desalin Water Treat 209:402–413. https://doi.org/10.5004/dwt.2021.26644
Georgekutty R, Seery MK, Pillai SC (2008) J Phys Chem C 112:13563–13570. https://doi.org/10.1021/jp802729a
Feng W, Yang X, He Z, Liu M (2021) J Phys D Appl Phys 54:135105. https://doi.org/10.1088/1361-6463/abd503
Johra FT, Jung WG (2015) Appl Catal A 491:52–57. https://doi.org/10.1016/j.apcata.2014.11.036
Cavalcante LS, Almeida MA, Avansi W Jr, Tranquilin RL, Longo E, Batista NC, Mastelaro VR (2012) Inorg Chem 51:10675–10687. https://doi.org/10.1021/ic300948n
Amouzegar Z, Naghizadeh R, Rezaie HR, Ghahari M, Aminzare M (2015) Ceram Int 41:8352–8359. https://doi.org/10.1016/j.ceramint.2014.09.119
Kaur M, Mehta SK, Kansal SK (2022) Environ Sci Pollut Res 30:8464–8484. https://doi.org/10.1007/s11356-022-18629-w
Kaur A, Anderson WA, Tanvir S, Kansal SK (2019) J Colloid Interface Sci 557:236–253. https://doi.org/10.1016/j.jcis.2019.09.017
Zhao H, Qian L, Lv H, Wang Y, Zhao G (2015) ChemCatChem 100:4148–4155. https://doi.org/10.1002/cctc.201500801
Thanh BN, Phung TT, Hong T, Ngo L, Thi L, Giang K (2015) Int J Nanotechnol 12:447–455. https://doi.org/10.1504/IJNT.2015.067902
Wu Y, Luo H, Zhang L (2015) Environ Sci Pollut Res Int 22:17238–17243. https://doi.org/10.1007/s11356-015-5364-z
Liang R, Shen L, Jing F, Qin N, Wu L (2015) ACS Appl Mater Interfaces 7:9507–9515. https://doi.org/10.1021/acsami.6b00028
Wu Y, Luo H, Wang H (2014) RSC Adv 4:40435–40438. https://doi.org/10.1039/C4RA07566H
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This work was financially supported by the Council of Scientific & Industrial Research (CSIR). Authors also appreciate the great support by the Sant Longowal Institute of Engineering & Technology to accomplish this work.
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Kaur, G., Sud, D. Fabrication of two-dimensional Zn/Cd-based metal-organic frameworks and their heterostructures as efficient photocatalysts for the degradation of industrial dyes. Transit Met Chem 48, 249–268 (2023). https://doi.org/10.1007/s11243-023-00539-6
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DOI: https://doi.org/10.1007/s11243-023-00539-6