Skip to main content

Advertisement

Log in

Fe- and Eu-doped TiO2 Photocatalytical Materials Prepared by High Energy Ball Milling

  • Original Paper
  • Published:
Topics in Catalysis Aims and scope Submit manuscript

Abstract

TiO2 nanopowders, doped with Fe3+ and Eu3+ were obtained by high-energy ball milling and their physical properties were investigated as a function of the doping content and ball milling time. A noticeable red shift and high photoactivity in the degradation and catalytic oxidation reactions of styrene and phenol were found for all doped specimens.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Bahnemann W, Muneer M, Haque MM (2007) Catal Today 124:133

    Article  CAS  Google Scholar 

  2. Ohno T, Tokieda K, Higashida S, Matsumura M (2003) Appl Catal A Gen 244:383

    Article  CAS  Google Scholar 

  3. He J, Zhao J, Shen T, Hidaka H, Serpone N (1997) J Phys Chem B 101:9027

    Article  CAS  Google Scholar 

  4. Cahen D, Hodes G, Graetzel M, Guillemoles JF, Riess I (2000) J Phys Chem B 104:2053

    Article  CAS  Google Scholar 

  5. Kormann C, Bahnemann D, Hoffmann M (1988) J Phys Chem 92:5196

    Article  CAS  Google Scholar 

  6. Soria J, Conesa JC, Augugliaro V, Palmisano L, Schiavello M, Sclafani A (1991) J Phys Chem 95:274

    Article  CAS  Google Scholar 

  7. Choi W, Termin A, Hoffmann MR (1994) J Phys Chem 98:13669

    Article  Google Scholar 

  8. Zhang Z, Wang C, Zakaria R, Ying JY (1998) J Phys Chem B 102:10871

    Article  CAS  Google Scholar 

  9. Cao Y, Zhang X, Yang W, Du H, Bai Y, Li T, Yao J (2000) Chem Mater 12:3445

    Article  CAS  Google Scholar 

  10. Zhou M, Yu J, Cheng B, Yu H (2005) Mater Chem Phys 93:159

    Article  CAS  Google Scholar 

  11. Zhu J, Chen F, Zhang J, Chen H, Anpo M (2006) J Photochem Photobiol A Chem 180:196

    Article  CAS  Google Scholar 

  12. Lee K, Lee NH, Shin SH, Lee HG, Kim SJ (2006) Mater Sci Eng B 129:109

    Article  CAS  Google Scholar 

  13. Colmenares JC, Aramendy MA, Marinas A, Marinas JM, Urbano FJ (2006) Appl Catal A Gen 306:120

    Article  CAS  Google Scholar 

  14. Xu AW, Gao Y (2002) J Catal 207:151

    Article  CAS  Google Scholar 

  15. Liu Z, Zhang J, Han B, Du J, Mu T, Wang Y, Sun Z (2005) Microporous Mesoporous Mater 81:169

    Article  CAS  Google Scholar 

  16. Zeng QG, Ding ZJ, Zhang ZM (2006) J Lumin 118:301

    Article  CAS  Google Scholar 

  17. Yang P, Lu C, Hua N, Du Y (2002) Mater Lett 57:794

    Article  CAS  Google Scholar 

  18. Matsuo S, Sakaguchi N, Yamada K, Matsuo T, Wakita H (2004) Appl Surf Sci 228:223

    Article  Google Scholar 

  19. Kim DH, Hong HS, Kim SJ, Song JS, Lee KS (2004) J Alloy Compd 375:259

    Article  CAS  Google Scholar 

  20. Shifu C, Lei C, Shen G, Gengyu C (2005) Chem Phys Lett 413:404

    Article  CAS  Google Scholar 

  21. Xiaoyan P, Dongmei J, Yan L, Xueming M (2006) J Magn Magn Mater 305:388

    Article  Google Scholar 

  22. Cordishi D, Burriesci N, D’Alba F, Petrera M, Polizzotti G, Schiavello M (1985) J Solid State Chem 56:182

    Article  Google Scholar 

  23. Shannon RD (1976) Acta Crystallogr A32:751

    CAS  Google Scholar 

  24. Zabinsky SI, Rehr JJ, Ankudinov A, Albers RC, Eller MJ (1995) Phys Rev B 52:2995

    Article  CAS  Google Scholar 

  25. Gennari FC, Pasquevich DM (2004) J Am Ceram Soc 82:1915

    Article  Google Scholar 

  26. Su C, Tseng C-M, Chen L-F, You B-H, Hsu B-C, Chen S-S (2006) Thin Solid Films 498:259

    Article  CAS  Google Scholar 

  27. Wagner CD, Riggs WM, Davis LE (1979) Handbook of X-ray photoelectron spectroscopy. Perkin-Elmer Corporation Physical Electronics Division, USA

    Google Scholar 

  28. Gudat W, Eastman D (1976) J Vac Sci Technol 13:831

    Article  CAS  Google Scholar 

  29. Alonso M, Cimino R, Horn K (1990) Phys Rev Lett 64:1947

    Article  CAS  Google Scholar 

  30. Descostes M, Mercier F, Thromat N, Beaucaire C, Gautier-Soyer M (2000) Appl Surf Sci 165:288

    Article  CAS  Google Scholar 

  31. Bhargava G, Gouzman I, Chun CM, Ramanarayanan TA, Bernasek SL (2007) Appl Surf Sci 253:4322

    Article  CAS  Google Scholar 

  32. Schneider WD, Laubschat C, Nowik I, Kaindl G (1981) Phys Rev B 24:5422

    Article  CAS  Google Scholar 

  33. Nilsson O, Norberg CH, Bergmark JE, Fahlman A, Nordling C, Siegbahn K (1968) Helv Phys Acta 41:1064

    CAS  Google Scholar 

  34. Kurmaev EZ, Cherkashenko VM, Neumann M (1998) J Electron Spectrosc Relat Phenomena 96:187

    Article  CAS  Google Scholar 

  35. Wertheim GK, Sampathkumaran EV, Laubschat C, Kaindl G (1985) Phys Rev B 31:6836

    Article  CAS  Google Scholar 

  36. Greegor RB, Lytle FW (1980) J Catal 63:476

    Article  CAS  Google Scholar 

  37. Jacobs JWM, Kampers FWH, Rikken JMG, Bulle-Lieuwma CWT, Koningsberger DC (1989) J Electrochem Soc 136:2914

    Article  CAS  Google Scholar 

  38. Balcells LI, Frontera C, Sandiumenge F, Roig A, Martínez B (2006) Appl Phys Lett 89:122501

    Article  Google Scholar 

  39. Li W, Frenkel AI, Woicik JC, Ni C, Ismat Shah S (2005) Phys Rev B 72:155315

    Article  Google Scholar 

  40. Tauc J, Grigorovici R, Vancu A (1966) Phys Status Solidi 15:627

    Article  CAS  Google Scholar 

  41. Delgass WN (1979) Spectroscopy in heterogeneous catalysis. Academic Press, New York

    Google Scholar 

  42. Miyake Y, Tada H (2004) J Chem Eng Jpn 37:630

    Article  CAS  Google Scholar 

  43. Oh SM, Kim SS, Lee JE, Ishigaki T, Park DW (2003) Thin Solid Films 435:252

    Article  CAS  Google Scholar 

  44. Litter MI, Navio JA (1996) J Photochem Photobiol A Chem 98:171

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Some of us (D.M. and C.M.T.) gratefully acknowledge the qualified assistance of Dr. Edmund Welter and Dr. Dariusz Zajac (Hasylab) during the EXAFS measurements, as well as the scientific support of Prof. Eberhardt Burkel (University of Rostock). The assistance of Dr. M. Feder in XRD investigations is also gratefully acknowledged.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Florin Vasiliu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vasiliu, F., Diamandescu, L., Macovei, D. et al. Fe- and Eu-doped TiO2 Photocatalytical Materials Prepared by High Energy Ball Milling. Top Catal 52, 544–556 (2009). https://doi.org/10.1007/s11244-009-9192-6

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11244-009-9192-6

Keywords

Navigation