Abstract
The isothermal and cyclic oxidation behavior of Haynes 282 (H282) processed by laser powder bed fusion and electron beam melting was compared to its cast counterpart during exposures in air at 800 and \(950~^{\circ }\hbox {C}\). The specific microstructure of the AM alloys compared to coarse-grain cast 282 resulted in differences in oxidation rates, internal oxidation and spallation behavior. At \(800~^{\circ }\hbox {C}\), faster Ti diffusion to the surface due to the smaller grain size of the AM alloys led to Ti doping of the \({\hbox {Cr}_{2}\hbox {O}_3}\) scale and faster oxidation rates. The higher density of grain boundaries also resulted in more pronounced internal oxidation. At \(950~^{\circ }\hbox {C}\), a duplex \({\hbox {Cr}_{2}\hbox {O}_3}\) scale was observed with a dense inner layer and porous cracked outer layer with embedded \({\hbox {TiO}_2}\) particles. The impact of the external and internal oxide compositions and oxidation-induced elemental depletions on the oxidation lifetime, creep properties and spallation behavior is discussed.
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Acknowledgements
The authors thank G. Garner, J. Wade, B. Johnston, T. Lowe, T. Jordan, V. Cox and C. O’Dell for the assistance with the experimental work and X. Chen at ORNL and Anand Kulkani at Siemens Corporation for providing us with the cast and LPBF H282 alloys, respectively. K. Kane, C. Parker and B.A. Pint are kindly acknowledged for their comments on the manuscript. The authors declare that they have no conflict of interest. Research was sponsored by the US Department of Energy, Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office, and Office of Fossil Energy, Crosscutting Research Program, under contract DE-AC05-00OR22725 with UT-Battelle LLC.
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Romedenne, M., Stack, P., Pillai, R. et al. Isothermal and Cyclic Oxidation of Haynes 282 Processed by Electron Beam Melting (EBM) and Laser Powder Bed Fusion (LPBF) in Dry Air at 800 and \(950~^{\circ }\hbox {C}\). JOM 74, 1–12 (2022). https://doi.org/10.1007/s11837-022-05201-7
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DOI: https://doi.org/10.1007/s11837-022-05201-7