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Strengthening synergistic effects between hard carbon and soft carbon enabled by connecting precursors at molecular level towards high-performance potassium ion batteries

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Abstract

Synergistic effects between hard carbons and soft carbons are proven to be helpful for improving the electrochemical performance of carbonaceous anode for potassium-ion batteries (PIBs). However, the phase separation of precursors limits the synergistic effects and improvement of electrochemical performance. Here, inspired by the esterification reaction, the precursors of two sorts of carbon are connected at the molecular level, which boosts the synergistic effects in hybrid carbon, resulting in excellent electrochemical kinetics and low charge/discharge voltage. Consequently, the hybrid carbon anode exhibited a high specific capacity of 121 mAh·g−1 at 3.2 A·g−1, a high-rate capability, and stable cycling performance. After 500 cycles at 1 A·g−1, the average capacity fading is only 0.078% per cycle.

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Acknowledgements

This work was supported by High-quality Development Project of Ministry of Industry and Information Technology of China (No. TC210H041), the Hundred Talents Program, the National Natural Science Foundation of China (No. 51872304), and Ningbo S&T Innovation 2025 Major Special Program (Nos. 2018B10024, 2019B10044, 2020Z101, and 2022Z022).

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Authors and Affiliations

  1. Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China

    Hongqiang Xu, Boshi Cheng, Quan Du, Yuting Zhang, Haojie Duan, Ishioma L. Egun, Bo Yin & Haiyong He

  2. University of Chinese Academy of Sciences, Beijing, 101400, China

    Hongqiang Xu & Yuting Zhang

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  1. Hongqiang Xu
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Correspondence to Bo Yin or Haiyong He.

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Strengthening synergistic effects between hard carbon and soft carbon enabled by connecting precursors at molecular level towards high-performance potassium ion batteries

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Xu, H., Cheng, B., Du, Q. et al. Strengthening synergistic effects between hard carbon and soft carbon enabled by connecting precursors at molecular level towards high-performance potassium ion batteries. Nano Res. 16, 10985–10991 (2023). https://doi.org/10.1007/s12274-023-5853-1

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