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Preparation of zeolite NaA for CO2 capture from nickel laterite residue

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Abstract

Zeolite NaA was successfully prepared from nickel laterite residue for the first time via a fusion-hydrothermal procedure. The structure and morphology of the as-synthesized zeolite NaA were characterized with a range of experimental techniques, such as X-ray diffraction, scanning electronic microscopy, and infrared spectroscopy. It was revealed that the structures of the produced zeolites were dependent on the molar ratios of the reactants and hydrothermal reaction conditions, so the synthesis conditions were optimized to obtain pure zeolite NaA. Adsorption of nitrogen and carbon dioxide on the prepared zeolite NaA was also measured and analyzed. The results showed that zeolite NaA could be prepared with reasonable purity, it had physicochemical properties comparable with zeolite NaA made from other methods, and it had excellent gas adsorption properties, thus demonstrating that zeolite NaA could be prepared from nickel laterite residue.

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References

  1. D.W. Breck, Zeolite Molecular Sieves, Wiley-Interscience, New York, 1974, p. 397.

    Google Scholar 

  2. S.M. Kuznicki, V.A. Bell, S. Nair, H.W. Hillhouse, R.M. Jacubinas, C.M. Braunbarth, B.H. Toby, and M. Tsapatsis, A titanosilicate molecular sieve with adjustable pores for size-selective adsorption of molecules, Nature, 412(2001), p. 720.

    Article  Google Scholar 

  3. S.M. Kuznicki, Preparation of Small-Pored Crystalline Titanium Molecular Sieve Zeolites, U.S. Patent, Appl.4938939, 1990.

    Google Scholar 

  4. J. Shang, G. Li, R. Singh, Q.F. Gu, K.M. Nairn, T.J. Bastow, N. Medhekar, C.M. Doherty, A.J. Hill, J.Z. Liu, and P.A. Webley, Discriminative separation of gases by a “molecular trapdoor” mechanism in chabazite zeolites, J. Am. Chem. Soc., 134(2012), p. 19246.

    Article  Google Scholar 

  5. N. Sapawe, A.A. Jalil, S. Triwahyono, M.I.A. Shah, R. Jusoh, N.F.M. Salleh, B.H. Hameed, and A.H. Karim, Cost-effective microwave rapid synthesis of zeolite NaA for removal of methylene blue, Chem. Eng. J., 229(2013), p. 388.

    Article  Google Scholar 

  6. I. Majchrzak-Kucęba and W. Nowak, A thermogravimetric study of the adsorption of CO2 on zeolites synthesized from fly ash, Thermochim. Acta, 437(2005), p. 67.

    Article  Google Scholar 

  7. L. Liu, R. Singh, P. Xiao, P.A. Webley, and Y. Zhai, Zeolite synthesis from waste fly ash and its application in CO2 capture from flue gas streams, Adsorption, 17(2011), p. 795.

    Article  Google Scholar 

  8. J.D.C. Izidoro, D.A. Fungaro, J.E. Abbott, and S. Wang, Synthesis of zeolites X and A from fly ashes for cadmium and zinc removal from aqueous solutions in single and binary ion systems, Fuel, 103(2013), p. 827.

    Article  Google Scholar 

  9. O. Font, N. Moreno, S. Díez, X. Querol, A. López-Soler, P. Coca, and F.G. Peña, Differential behaviour of combustion and gasification fly ash from Puertollano Power Plants (Spain) for the synthesis of zeolites and silica extraction, J. Hazard. Mater., 166(2009), p. 94.

    Article  Google Scholar 

  10. R.G. Bell, R.A. Jackson, and C.R.A. Catlow, Löwenstein’s rule in zeolite A: a computational study, Zeolites, 12(1992), p. 870.

    Article  Google Scholar 

  11. M.P. Moisés, C.T.P. da Silva, J.G. Meneguin, E.M. Girotto, and E. Radovanovic, Synthesis of zeolite NaA from sugarcane bagasse ash, Mater. Lett., 108(2013), p. 243.

    Article  Google Scholar 

  12. V.Y. Prokof’ev, N.E. Gordina, and A.M. Efremov, Synthesis of type A zeolite from mechanoactivated metakaolin mixtures, J. Mater. Sci., 48(2013), p. 6276.

    Article  Google Scholar 

  13. W.N. Mu, Y.C. Zhai, and Y. Liu, Leaching of magnesium from desiliconization slag of nickel laterite ores by carbonation process, Trans. Nonferrous Met. Soc. China, 20(2010), Suppl. 1, p. s87.

    Article  Google Scholar 

  14. C.W. Purnnomo, C. Salim, and H. Hinode, Synthesis of pure Na-X and Na-A zeolite from bagasse fly ash, Microporous Mesoporous Mater., 162(2012), p. 6.

    Article  Google Scholar 

  15. R.V. Siriwardane, M.S. Shen, E.P. Fisher, and J.A. Poston, Adsorption of CO2 on molecular sieves and activated carbon, Energy Fuels, 15(2001), p. 279.

    Article  Google Scholar 

  16. M. Machida, M. Uto, D. Kurogi, and T. Kijima, MnOx-CeO2 binary oxides for catalytic NOx sorption at low temperatures: sorptive removal of NOx, Chem. Mater., 12(2000), No. 10, p. 3158.

    Article  Google Scholar 

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Correspondence to Li-ying Liu.

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Du, T., Liu, Ly., Xiao, P. et al. Preparation of zeolite NaA for CO2 capture from nickel laterite residue. Int J Miner Metall Mater 21, 820–825 (2014). https://doi.org/10.1007/s12613-014-0976-8

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  • DOI: https://doi.org/10.1007/s12613-014-0976-8

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