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A Feasible Route to Produce 30 MPa Adhesion Strength of Electrochemically Deposited Hydroxyapatite (HA) on Titanium (Ti6Al4V) Alloy

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Abstract

Ti6Al4V alloy, an α + β titanium alloy having good biocompatibility, low density, high strength and a better resistance to corrosion is an excellent candidate for bridges and implants. Hydroxyapatite (HA), a calcium phosphate (Ca10(PO4)6(OH)2) mineral having similar chemical composition with the hard tissues of human bones, was electrochemically deposited on Ti6Al4V alloy grade-5. The surface activity of substrate was increased by a uniform TiO2 film, achieved by grinding, polishing, pretreatment with anodization and alkali treatment. Electrochemical deposition was done by HA powder-ethanol suspension with an antibacterial binder called chitosan at set parameters of 20 V for 1 h at pH 4. The adhesion ability and polarization behavior of HA-coated Ti6Al4V alloy was observed. The anodized, HA-coated, and a bare substrate alloy samples were examined in a bio-simulated solution of ringer’s lactate for polarization testing. SEM and EDAX analysis were performed for HA powder and HA-deposited sample to observe the surface morphology with elemental compositions. Adhesion test (Shimadzu AGS X series tensile testing machine at 25 °C and 60% relative humidity) was performed to check the coating adhesiveness with the metallic substrate, and the observed value was upto 30 MPa. Herein, the electrochemical-deposited HA-coated samples were more resistant to dissolution and showed 2 times better corrosion resistance than bare metal. The bonding strength achieved in this work was also 30 MPa which is greater than required for tooth fixation and root implants (20 MPa).

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Authors and Affiliations

  1. Institute of Metallurgy and Materials Engineering, Faculty of Chemical and Materials Engineering, University of the Punjab, Lahore, Pakistan

    Nosheen Maryam Awan, Muhammad Umar Manzoor, Faraz Hussain, Zaeem Ur Rehman & Muhammad Ishtiaq

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  1. Nosheen Maryam Awan
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Awan, N.M., Manzoor, M.U., Hussain, F. et al. A Feasible Route to Produce 30 MPa Adhesion Strength of Electrochemically Deposited Hydroxyapatite (HA) on Titanium (Ti6Al4V) Alloy. Trans Indian Inst Met 76, 1653–1660 (2023). https://doi.org/10.1007/s12666-023-02876-7

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