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Removal of methylene blue and crystal violet in binary aqueous solution by magnetic Terminalia catappa kernel shell biosorbent using Box–Behnken design

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Abstract

Due to their low cost, availability, and environmental friendliness, biosorbents derived from renewable sources are appropriate for wastewater treatment. This study proposes the Terminalia catappa fruit kernel shell-Fe3O4 as an effective biosorbent for the removal of Crystal Violet (CV) and Methylene Blue (MB) dyes from environmental fluids. The Box–Behnken design was used in conjunction with the surface response methodology to optimize the CV and MB absorption processes. Under the optimum conditions of pH 6.7, an adsorbent amount of 69 mg, a CV concentration of 30 mg/L, MB concentration of 26 mg/L, and contact time of 6 min, 92.61% and 90.89% of the CV and MB absorption efficiencies were observed. The development of isotherms in binary solution revealed that the Extended Langmuir multicomponent isotherm best described the adsorption process and was also consistent with quasi-quadratic kinetics. The biosorbent capacity does not reduce after five regeneration cycles and is still efficient.

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References

  1. M. Hajjaji, A. Alami, A. El Bouadili, J. Hazard. Mater. 135, 188 (2006)

    Article  CAS  PubMed  Google Scholar 

  2. T. Albanis, D. Hela, T. Sakellarides, T. Danis, Global Nest Int. J 2, 237 (2000)

    Google Scholar 

  3. D. Ghosh, K.G. Bhattacharyya, Appl. Clay Sci. 20, 295 (2002)

    Article  CAS  Google Scholar 

  4. J. Hoslett, H. Ghazal, N. Mohamad, H. Jouhara, Sci. Total Environ. 714, 136832 (2020)

    Article  CAS  PubMed  Google Scholar 

  5. B. Can-Terzi, A. Goren, H. Okten, S. Sofuoglu, Environ. Technol 22, 101432 (2021)

    CAS  Google Scholar 

  6. L. Tang, J. Yu, Y. Pang, G. Zeng, Y. Deng, J. Wang, X. Ren, S. Ye, B. Peng, H. Feng, Chem. Eng. J. 336, 160 (2018)

    Article  CAS  Google Scholar 

  7. J. Liu, Y. Wang, Y. Fang, T. Mwamulima, S. Song, C. Peng, J. Mol. Liq. 250, 468 (2018)

    Article  CAS  Google Scholar 

  8. N. Nasuha, B. Hameed, A.T.M. Din, J. Hazard. Mater. 175, 126 (2010)

    Article  CAS  PubMed  Google Scholar 

  9. K.G. Bhattacharyya, A. Sharma, Dyes. Pigm. 65, 51 (2005)

    Article  CAS  Google Scholar 

  10. B.T. Gemici, H.U. Ozel, H.B. Ozel, Environ. Technol. 22, 101501 (2021)

    CAS  Google Scholar 

  11. A. Adak, M. Bandyopadhyay, A. Pal, Dyes. Pigm. 69, 245 (2006)

    Article  CAS  Google Scholar 

  12. Y.-R. Huang, Y. Kong, H.-Z. Li, X.-M. Wei, Environ. Technol 18, 100780 (2020)

    Google Scholar 

  13. S.K. Low, M.C. Tan, N.L. Chin, Ultrason. Sonochem. 48, 64 (2018)

    Article  CAS  PubMed  Google Scholar 

  14. L. Pereira, M. Alves, Environ. Dev. Sustain., Springer 2012.

  15. Z. Carmen, S. Daniela, Textile organic dyes-characteristics, polluting effects and separation/elimination procedures from industrial effluents-a critical overview, IntechOpen Rijeka (2012). pp. 89–90

  16. M. Ashrafi, M. Chamjangali, G. Bagherian, N. Goudarzi, S. Kavian, Water. Treat. 88, 207 (2017)

    CAS  Google Scholar 

  17. S. Santaeufemia, J. Abalde, E. Torres, J. Appl. Phycol. 33, 3071 (2021)

    Article  CAS  Google Scholar 

  18. A. Khodabandehloo, A. Rahbar-Kelishami, H. Shayesteh, J. Mol. Liq. 244, 540 (2017)

    Article  CAS  Google Scholar 

  19. X. Peng, F. Hu, T. Zhang, F. Qiu, H. Dai, Bioresour. Technol. 249, 924 (2018)

    Article  CAS  PubMed  Google Scholar 

  20. L. Bulgariu, D. Bulgariu, J. Clean. Prod. 197, 875 (2018)

    Article  CAS  Google Scholar 

  21. D. Sud, G. Mahajan, M. Kaur, Bioresour. Technol. 99, 6017 (2008)

    Article  CAS  PubMed  Google Scholar 

  22. M. Villen-Guzman, M.D.M. Cerrillo-Gonzalez, J. Paz-Garcia, J.M. Rodriguez-Maroto, B. Arhoun, Environ. Technol 21, 101380 (2021)

    CAS  Google Scholar 

  23. R. Lafi. N. Hamdi, A. Hafiane, Desalin. Water. Treat. 56 (2015) 722.

  24. N. Mehmandost, N. Goudarzi, M.A. Chamjangali, G. Bagherian, Spectrochim. Acta A Mol. Biomol. Spectrosc. 265, 120292 (2022)

    Article  CAS  PubMed  Google Scholar 

  25. M. Mathivanan, S. Syed Abdul Rahman, R. Vedachalam, S. Karuppiah, Int. J. Phytoremediation 23 (2021) 982.

  26. S. Shoukat, H.N. Bhatti, M. Iqbal, S. Noreen, Microporous Mesoporous Mater. 239, 180 (2017)

    Article  CAS  Google Scholar 

  27. S.D. Pardeshi, J.P. Sonar, A. Zine, S. Thore, J. Iran. Chem. Soc. 10, 1159 (2013)

    Article  CAS  Google Scholar 

  28. A.S. Takabi, M. Shirani, A. Semnani, Environ. Technol 24, 101947 (2021)

    CAS  Google Scholar 

  29. P. Grassi, F.C. Drumm, J. Georgin, D.S.P. Franco, G.L. Dotto, E.L. Foletto, S.L. Jahn, Environ. Sci. Pollut. Res. 28, 6771 (2021)

    Article  CAS  Google Scholar 

  30. M.A. Bezerra, R.E. Santelli, E.P. Oliveira, L.S. Villar, L.A. Escaleira, Talanta 76, 965 (2008)

    Article  CAS  PubMed  Google Scholar 

  31. K.P. Singh, S. Gupta, A.K. Singh, S. Sinha, J. Hazard. Mater. 186, 1462 (2011)

    Article  CAS  PubMed  Google Scholar 

  32. L. Mutihac, R. Mutihac, Anal. Chim. Acta 612, 1 (2008)

    Article  CAS  PubMed  Google Scholar 

  33. S. Chakraborty, S. Chowdhury, P.D. Saha, Carbohydr. Polym. 86, 1533 (2011)

    Article  CAS  Google Scholar 

  34. M. Šćiban, M. Klašnja, B. Škrbić, J. Hazard. Mater. 136, 266 (2006)

    Article  PubMed  CAS  Google Scholar 

  35. S.A. Baig, J. Zhu, N. Muhammad, T. Sheng, X. Xu, Biomass Bioenergy 71, 299 (2014)

    Article  CAS  Google Scholar 

  36. P. Panneerselvam, N. Morad, K.A. Tan, J. Hazard. Mater. 186, 160 (2011)

    Article  CAS  PubMed  Google Scholar 

  37. K.K. Choy, J.F. Porter, G. McKay, J. Chem. Eng. Data 45, 575 (2000)

    Article  CAS  Google Scholar 

  38. G. Crini, E. Lichtfouse, Green adsorbents for pollutant removal: fundamentals and design, Springer (2018). pp. 14–17

  39. S. Żółtowska-Aksamitowska, P. Bartczak, J. Zembrzuska, T. Jesionowski, Sci. Total Environ. 612, 1223 (2018)

    Article  PubMed  CAS  Google Scholar 

  40. M. Danish, W.A. Khanday, R. Hashim, N.S.B. Sulaiman, M.N. Akhtar, M. Nizami, Ecotoxicol. Environ. Saf. 139, 280 (2017)

    Article  CAS  PubMed  Google Scholar 

  41. N. Mehmandost, M.T. García-Valverde, M.L. Soriano, N. Goudarzi, R. Lucena, M.A. Chamjangali, S. Cardenas, J. Environ. Chem. Eng. 8, 104481 (2020)

    Article  CAS  Google Scholar 

  42. J. Ríos-Gómez, R. Lucena, S. Cárdenas, Microchem. J. 133, 90 (2017)

    Article  CAS  Google Scholar 

  43. J. Cheriaa, M. Khaireddine, M. Rouabhia, A. Bakhrouf, Sci. World. J. 2012 (2012).

  44. A. S. Sartape, S. A. Patil, S. K. Patil, S. T. Salunkhe, S. S. Kolekar, Desalin. Water. Treat. 53 (2015) 99.

  45. S. Yavari. N. M. Mahmodi. P. Teymouri. B. Shahmoradi, A. Maleki, J. Taiwan. Inst. Chem. Eng. 59 (2016) 320.

  46. F. J. Sotomayor, K. A. Cychosz, M. Thommes, Acc. Mater. Surf. Res 3 (2018) 34.

  47. S. Chen, Q. Yue, B. Gao, X. Xu, J. Colloid Interface Sci. 349 (2010) 256.

  48. T. H. Tran, A. H. Le, T. H. Pham, D. T. Nguyen, S. W. Chang, W. J. Chung, D. D. Nguyen, Sci. Total Environ. 725 (2020) 138325.

  49. M. Turabık, B. Gozmen, CLEAN–Soil Air Water 41, 1080 (2013)

    Article  CAS  Google Scholar 

  50. M. Ashrafi, G. Bagherian, M. A. Chamjangali, N. Goudarzi, A. H. Amin, Mater. Res. Express 5 (2018) 065510.

  51. Z. Du, T. Zheng, P. Wang, L. Hao, Y. Wang, Bioresour. Technol. 201 (2016) 41.

  52. G.O. El-Sayed, Desalination 272, 225 (2011)

    Article  CAS  Google Scholar 

  53. A. Nieva, L. Avena, M. Pascual, K. Pamintuan, Characterization of Powdered Pineapple (Ananas comosus) Crown Leaves as Adsorbent for Crystal Violet in Aqueous Solutions, IOP Publishing (2020). pp. 65–69

  54. P. Das, P. Banerjee, S. Mondal, Environ. Sci. Pollut. Res. 22 (2015) 1318.

  55. K. V. Kumar, V. Ramamurthi, S. Sivanesan, J. Colloid Interface Sci. 284 (2005) 14.

  56. M. U. Dural, L. Cavas, S. K. Papageorgiou, F. K. Katsaros, Chem. Eng. J. 168 (2011) 77.

  57. M. Bounaas, A. Bouguettoucha, D. Chebli, J. M. Gatica, H. Vidal, Arabian Journal for Science and Engineering 46 (2021) 325.

  58. T. C. Andrade Siqueira, I. Zanette da Silva, A. J. Rubio, R. Bergamasco, F. Gasparotto, E. Aparecida de Souza Paccola, N. Ueda Yamaguchi, Int. J. Env. Res. Public Health 17 (2020) 526.

  59. J. Bellot, J. Condoret, Process Biochem. 28, 365 (1993)

    Article  CAS  Google Scholar 

  60. K. Vijayaraghavan, Y.-S. Yun, J. Hazard. Mater. 153, 478 (2008)

    Article  CAS  PubMed  Google Scholar 

  61. Y.-S. Ho, G. McKay, Process Biochem. 34, 451 (1999)

    Article  CAS  Google Scholar 

  62. C. Sarici-Ozdemir, Physicochem. Probl. Miner. Proc. 48 (2012).

  63. S. S. Baral. S. N. Das, P. Rath, Biochem. Eng. J. 31 (2006) 216.

  64. M. B. Gholivand. Y. Yamini. M. Dayeni. S. Seidi, E. Tahmasebi, J. Environ. Chem. Eng. 3 (2015) 529.

  65. W. Stawiński. A. Węgrzyn. T. Dańko. O. Freitas. S. Figueiredo, L. Chmielarz, Chemosphere 173 (2017) 107.

  66. G. Z. Kyzas. D. N. Bikiaris, N. K. Lazaridis, J. Chem. Eng. 149 (2009) 263.

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This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.

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Authors and Affiliations

  1. Faculty of Chemistry, Shahrood University of Technology, P.O. Box 316, Shahrood, Iran

    Nasrin Mehmandost, Nasser Goudarzi, Mansour Arab Chamjangali & Ghadamali Bagherian

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  1. Nasrin Mehmandost
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  2. Nasser Goudarzi
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  3. Mansour Arab Chamjangali
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  4. Ghadamali Bagherian
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Correspondence to Nasser Goudarzi.

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Mehmandost, N., Goudarzi, N., Arab Chamjangali, M. et al. Removal of methylene blue and crystal violet in binary aqueous solution by magnetic Terminalia catappa kernel shell biosorbent using Box–Behnken design. J IRAN CHEM SOC 19, 3769–3781 (2022). https://doi.org/10.1007/s13738-022-02552-5

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