Abstract
The acyl thioacetamide-group chelated nanofiber was prepared from polyacrylonitrile(PAN) fiber with thioacetamide as vulcanization agent by an electrospinning process combined with chemical modification. It was found that the chelated nanofiber displays a high adsorption capacity and adsorption selectivity for Ag(I) ions from aqueous systems. The adsorption capacity of Ag(I) ions on chelated nanofiber increases with the increase of adsorption time. Kinetics of the Ag(I) ions adsorption was found to follow pseudo-second-order rate equation. Based on the characterization results, a possible mechanism of Ag(I) ions adsorbed on the acyl thioacetamide-group chelated nanofiber was proposed. The chelated nanofiber could not only chelate to Ag(I) ions but also reduce them. This study provides a promising nanofiber material for removing heavy metal ions.
Similar content being viewed by others
References
Liu R. X., Li Y., Tang H. X., J. Appl. Polym. Sci., 2002, 83, 1608
Atia A. A., Donia A. M., Yousif A. M., React. Funct. Polym., 2003, 56, 75
Baba Y., Ohe K., Kawasaki Y., Kolev S. D., React. Funct. Polym., 2006, 66, 1158
Zuo G., Muhammed M., React. Funct. Polym., 1995, 27, 187
Li F. H., Fu X. R., Huang J., Zhai J. P., Chem. Res. Chinese Universities, 2012, 28(4), 559
Kavakli P. A., Guven O., J. Appl. Polym. Sci., 2004, 93, 1705
Deng S., Bai R., Water Res., 2004, 38, 2424
Deng S., Bai R., Chen J. P., Langmuir, 2003, 19, 5058
Ma N., Yang Y., Chen S., Zhang Q., J. Hazard. Mater., 2009, 171, 288
Liu R., Tang H., Zhang B., Chemosphere, 1999, 38, 3169
Zhao D. Z., Jing S. B., Xu J. N., Yang H., Zheng W., Song T. Y., Zhang P., Chem. Res. Chinese Universities, 2013, 29(4), 793
Liu J., Wang H. L., Lü C. X., Liu H. F., Guo Z. X., Kang C. L., Chem. Res. Chinese Universities, 2013, 29(3), 445
Wang W., Yang Q. B., Sun L. Wang H. G., Zhang C. Q., Fei X. L., Sun M. D., Li Y. X., J. Hazard. Mater., 2011, 194, 185
Horzum N., Shahwan T., Parlak O., Demir M. M., Chem. Eng. J., 2012, 213, 41
Li X., Zhang C. C., Zhao R., Lu X. F., Xu X. R., Jia X. T., Wang C., Li L. J., Chem. Eng. J., 2013, 229, 420
Zhao Z. X., Ma B. W., Liang Z. H., Yuan S. G., Zhu S. Q., Ion Exchange Adsorpt., 2006, 22, 392
Liu F. F., Teng S. X., Song R. H., Wang S. G., Desalination, 2010, 263, 11
Wang Y. Z., Li Y. X., Yang S. T., Zhang G. L., An D. M., Wang C., Yang Q. B., Chen X. S., Jing X. B., Wei Y., Nanotechnology, 2006, 17, 3304
Wang F., Lai Y. J., Zhao B. Y., Hu X. B., Zhang D., Hu K. A., Chem. Commun., 2010, 46, 3782
Chang X., Wang Y., Zhao R., Anal. Bioanal. Chem., 2003, 377, 757
Author information
Authors and Affiliations
Corresponding author
Additional information
Supported by the National Natural Science Foundation of China(Nos.21274052, 51303060) and the Science and Technology Department Project of Jilin Province, China(No.20130206064GX).
Rights and permissions
About this article
Cite this article
Zhang, C., Li, X., Zheng, T. et al. Acyl thioacetamide-group chelated nanofiber to adsorb silver ions from aqueous systems. Chem. Res. Chin. Univ. 30, 685–689 (2014). https://doi.org/10.1007/s40242-014-4190-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40242-014-4190-z