Hydroxyapatite mineralization and demineralization in the presence of synthetic phosphorylated pentapeptides
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Binding mechanism and binding free energy of amino acids and citrate to hydroxyapatite surfaces as a function of crystallographic facet, pH, and electrolytes
2022, Journal of Colloid and Interface ScienceCitation Excerpt :Peptides derived from known HAP-binding proteins such as statherin and bone sialoprotein are known to control HAP growth [10]. The peptide sequences largely consist of acidic amino acid residues [11,77], and previous experiments have shown that Glu6 peptides bind strongly to HAP while Glu5Leu and Glu4Leu2 have increasingly weaker binding affinity [8,78]. These findings add evidence for the importance of acidic amino acids in HAP binding peptides.
Silk fibroin promotes mineralization of gellan gum hydrogels
2020, International Journal of Biological MacromoleculesCitation Excerpt :The formation of flake-like HAp on SBF treated surfaces was well supported the earlier reports of precipitation of flake-like HAps in presence of amino acids like Gly, Glu, Asp and Ser [23–25]. However, the presence of poly-Glu or poly-Asp inhibits the growth of HAp crystals, while present in solution, which may explain the formation of spherical HAps on surfaces treated with culture medium [26]. It is hypothesized that one or more mineralization nucleators escape from bone matrix into blood and constitute components of animal serum [27].
Dairy products and oral health
2007, Functional Dairy Products: Second EditionSolid state NMR studies of molecular recognition at protein-mineral interfaces
2007, Progress in Nuclear Magnetic Resonance SpectroscopyHuman dental plaque microcosm biofilms: Effect of nutrient variation on calcium phosphate deposition and growth
2007, Archives of Oral BiologyCitation Excerpt :We have shown that the generation of an alkaline pH is an important factor modulating mineral deposition in vitro.7 Other contributing factors include bacterial and environmental8 nucleation9 and inhibitor/promotor mechanisms.10,11 Crystal formation is initiated by nucleation onto matrix or exposed cell nucleators.