Homogeneous catalysis by transition metal oxygen anion clusters

doi:10.1016/0010-8545(95)01141-B

Coordination Chemistry Reviews

Volume 143, September 1995, Pages 407-455

https://doi.org/10.1016/0010-8545(95)01141-B Get rights and content

Abstract

This review provides a thorough discussion of homogeneous catalysis by transition metal oxygen anion clusters (polyoxometalates), with a focus on mechanism. The primary catalysts examined are mixed addenda and d-electron-transition-metal-substituted polyoxometalate (TMSP) complexes. The unusual versatility and tunability of these catalysts and their compatibility with environmentally and economically attractive conditions (solvents, oxidants, etc.) are outlined. A general compilation of the reactions, including catalytic electrooxidations or electroreductions, reported to date is given. Selected examples involving different classes of catalysts, different organic substrates and transformations, and mechanistic information are covered.

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Homogeneous catalysis by transition metal oxygen anion clusters

Abstract

Coord. Chem. Rev.

Coord. Chem. Rev.

Appl. Catal.

Appl. Catal.

J. Mol. Catal.

Coord. Chem. Rev.

J. Mol. Catal.

J. Mol. Catal.

Coord. Chem. Rev.

Coord. Chem. Rev.

J. Biol. Chem.

J. Biol. Chem.

Chem. Eng. News

J. Mol. Catal.

Science

Chem. Rev.

Mol. Eng.

Acc. Chem. Res.

Rec. Trav. Chim. Pays Bas-J. R. Netherlands Chem. Soc.

Pure Appl. Chem.

Russ. Chem. Rev.

Usp. Khim.

Russ. Chem. Rev.

Catal. Rev.-Sci. Eng.

Stud. Surf. Sci. Catal.

Yuki Gosei Kagaku Kyokaishi

Chem. Soc. Rev.

Heteropoly and Isopoly Oxometalates

Angew. Chem., Int. Ed. Engl.

Yuki Gosei Kagaku Kyokaishi

J. Chem. Soc. Dalton Trans.

New J. Chem.

Inorg. Chem.

J. Am. Chem. Soc.

J. Org. Chem.

Chem. Lett.