Lanthanide complexes—II: Complexes of 1:10-phenanthroline with lanthanide acetates and nitrates

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Abstract

Well-crystalline, thermally stable complexes of the types M(CH3COO)3(phen) and M(NO3)3 (phen)2, where M = all the lanthanides except Pm and phen = 1:10-phenanthroline, have been isolated. Magnetic moments and infra-red spectra are reported and structures are discussed.

References (7)

  • F.A. Hart et al.

    J. Inorg. Nucl. Chem.

    (1964)
  • S.P. Sinha

    Spectrochim. Acta

    (1964)
  • F.A. Hart et al.
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    1,10-Phenanthroline (phen) forms a variety of complexes with rare earth elements. One of the first complexes of this type was reported by Hart and Laming [12,13]. They proposed the formula of [Ln(phen)2Cl3OH2] and [Ln(phen)3(NCS)3] for this complexes but no crystal structure was reported [12,13].

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J. Inorg. Nucl. Chem.26, 579 (1964) is to be considered Part I of this series.

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