Darstellung und eigenschaften der azidchloride SnCl3N3, TiCl3N3 und VOCl2N3

doi:10.1016/0022-1902(65)80441-9

Journal of Inorganic and Nuclear Chemistry

Volume 27, Issue 4, April 1965, Pages 809-815

https://doi.org/10.1016/0022-1902(65)80441-9 Get rights and content

Zusammenfassung

Gasförmiges Chlorazid reagiert bei O°C in guter Ausbeute mit SnCl₄, TiCl₄ und VOCl₃ unter Bildung der kristallinen, hygroskopischen, explosiven Azidchloride SnCl₃N₃, TiCl₃N₃ und VOCl₂N₃. Nach den IR-Spektren liegen Inselstrukturen vor mit weitgehend homöopolaren MN₃-Bindungen. (M = Sn, Ti Symmetrie C_3v; M = V Symmetrie C_s.) Unter Lösungsmitteleinfluβ spalten TiCl₃N₃ und VOCl₂N₃ Stickstoff und Chlor ab, wobei sich die reinen, polymeren Nitridverbindungen TiNCl bzw. VON bilden.

Abstract

By reaction of gaseous chlorine azide with SnCl₄, TiCl₄ and VOCl₃ at 0°C the crystalline, hygroscopic, explosive Azidechlorides SnCl₃N₃, TiCl₃N₃ and VOCl₃N₃ respectively can be obtained in good yields. Infra-red spectra show these compounds to be island-structures with great degree of nonpolar MN₃-bondings (M = Sn, Ti symmetry C_3v; M = V symmetry C_s). By interaction of solvents TiCl₃N₃ and VOCl₂N₃ split off N₂ and Cl₂ and the well-defined nitride-compounds TiNCl and VON are obtainable.

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Darstellung und eigenschaften der azidchloride SnCl3N3, TiCl3N3 und VOCl2N3

Zusammenfassung

Abstract

Spectrochim. Acta

Angew. Chem.

Z. anorg. Chem.

Z. anorg. Chem.

Angew. Chem.

Acta physikochem. URSS

Z. anorg. Chem.

Ber. Dtsch. Chem. Ges.

Z. anorg. Chem.

Darstellung und eigenschaften der azidchloride SnCl₃N₃, TiCl₃N₃ und VOCl₂N₃