Journal of Inorganic and Nuclear Chemistry
Chemistry of oxo-metal ions—III: 2,2′-bipyridinium oxopentachloromolybdate(V) and its derivatives
References (11)
- et al.
J. inorg. nucl. Chem.
(1971) J. inorg. nucl. Chem.
(1963)J. inorg. nucl. Chem.
(1964)J. inorg. nucl. Chem.
(1965)- et al.
J. chem. Soc.
(1927)
Cited by (25)
The reactions of MoOCl<inf>4</inf> with neutral group 15 and 16 ligands and a re-investigation of some N-donor ligand complexes of MoOCl<inf>3</inf>
2021, PolyhedronCitation Excerpt :The main bands in the IR spectra (ν(MoO), ν(MoCl) and the strong bands of the diimine) were essentially identical to those in the red isomer, and in addition, some of the spectra (but not all) showed other weaker bands, absent in the spectra of the red isomer (S3, S13). Very similar spectra for the two ‘isomers’ are also reported in the literature, although data quality are variable with doubts about the purity of some samples raised by other authors, and often data below 500 cm−1 were not reported [22–26,39]. As would be expected from the different colours, the greatest differences are in the UV/visible spectra.
New mononuclear and binuclear oxomolybdenum(V) complexes containing N[sbnd]N chelator: Syntheses, DFT calculations, interaction with BSA protein and in vitro cytotoxic activity
2019, Journal of Inorganic BiochemistryCitation Excerpt :Comparatively, Mo(V) complexes have been less discussed due to their instability. The chemistry of Mo(V) is dominated by the paramagnetic mononuclear molybdenyl cation MoO3+ and diamagnetic binuclear oxo-bridged Mo2O34+ or Mo2O42+ cores [8–14]. The treatment and eradication of cancer involves chemotherapy as one of the important techniques [15].
Photoredox reactions of oxomolybdenum(V) with phosphines
2000, PolyhedronCitation Excerpt :We believe a more likely explanation of the maroon color is the non-oxo Mo(IV) complex MoCl4(PEt3)2. This would be closely related to the Mo(III) anion MoCl4(PEt3)2 − already observed in this system, and other trans-MoCl4(PR3)2 complexes have been reported to be maroon [37,44], though no electronic absorption spectral data have been published. Thus, PEt3 reacts with Mo(V) to give the oxygen atom transfer products of Scheme 1, and other products.
A novel route to molybdenum(V) 1,2-Bis(diphenylphosphine)ethane complexes
1981, Inorganica Chimica ActaChemistry of oxometal ion-XIII. Studies on molybdenyl oxalates
1979, Journal of Inorganic and Nuclear Chemistry