Crystalline insoluble acid salts of tetravalent metals—XXIII: Preparation and main ion exchange properties of highly hydrated zirconium bis monohydrogen orthophosphates☆
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The synthesis and applications of α-zirconium phosphate
2020, Chinese Chemical LettersCitation Excerpt :This compound was synthesized by refluxing the amorphous zirconium phosphate with concentrated phosphoric acid [4,8]. Since then, many other crystalline ZrP has been synthesized, e.g., β-Zr(PO4)(H2PO4) and γ-Zr(PO4)(H2PO4)·2H2O [9–12], θ-Zr(HPO4)2·6H2O [13–17], and τ- and τ'-Zr(HPO4)2 with three-dimensional frameworks [18,19]. Of the crystalline zirconium phosphates, α-ZrP has been the one most studied.
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This work was supported by Grant No. 74/00409 from the Istituto di Ricerca sulle Acque of C.N.R.
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