Structural trends in the lanthanide trihydroxides
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2017, Applied Clay ScienceCitation Excerpt :For Y(III) adsorbed at the surface of hectorite, the NP associated amount of Y(III) is expected to follow the surface area to volume ratio, and thus the Mg:Y ratio is expected to change with the NP size (Bouby et al., 2015). The X-ray diffractogram of Y(OH)3 could be modeled (Fig. 1) considering only the structure reported by Beall et al. (1977), no separate phase was detected. The X-ray diffractogram of YcopBru indicated the presence of only magnesium hydroxide, and a good fit to the data was obtained considering only brucite.
Crystal structure details of La- and Bi-substituted hydroxyapatites: Evidence for Lao<sup>+</sup> and BiO<sup>+</sup> with a very short metal-oxygen bond
2016, Journal of Solid State ChemistryCitation Excerpt :We could not find reliable data in the inorganic ICSD data base for La–O bonds below 2.37 Å putting aside calcium oxyapatite structure (see [9]). Typical shortest distances are 2.47 Å in LaPO4 (c.n.=9) [34], 2.39 Å in LaOCl (c.n.=4(O)+6(Cl)) [35], and 2.55 Å in La(OH)3 (c.n.=9) [36]. Therefore the La–O distance determined in our work is the shortest to our knowledge.
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