“Cation-cation” complexes of pentavalent actinides—I: Spectrophotometric study of complexes between neptunium (V) and UO22+ and NpO22+ ions in aqueous perchloric and nitric solutions
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NUCLEAR MAGNETIC RELAXATION STUDIES ON ACTINIDE IONS AND MODELS OF ACTINIDE COMPLEXES
2005, Advances in Inorganic ChemistryCitation Excerpt :One oxygen atom of an NpO+2 unit could be coordinated to the central metal atom of another cation instead of a water molecule or bonds could be formed by solvent molecules between two cations. Recent EXAFS studies did not allow a clear distinction between these two binding modes (56) but actinyl ions are known to easily interact with oxygen donor molecules (57,58). Glebov and Tikhonov (59) deduced from variable-temperature relaxivity measurements in concentrated nitrate media that the interaction between NpO+2 and UO2+2 increases the rotational correlation time of the former by a factor of 4.
Insights into the Mechanism of Neptunium Oxidation to the Heptavalent State
2024, Chemistry - A European JournalDensity Functional Theory Guided Investigation of Ligand-Induced Neptunyl-Neptunyl Interactions
2023, European Journal of Inorganic ChemistryNeptunium redox speciation and determination of its total concentration in dissolved fuel simulant solutions by spectrophotometry
2022, Journal of Radioanalytical and Nuclear Chemistry
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