Synthesis and characterization of divalent-europium (Eu2+) compounds, EuB4O7, EuB2O4 and Eu2B2O5
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2018, Journal of Solid State ChemistryCitation Excerpt :The less pronounced bands between 500 and 700 cm−1 can be assigned to bending vibrations of BO3 and BO4 groups [34]. The strong bands between 1600 and 850 cm−1 are typically B–O stretching vibrations, whereby bands of [BO3]3- vibrations are expected between 1450 and 1200 cm−1 [35–37]. Furthermore, the absorption peaks of the asymmetric and symmetric stretching modes of the BO4 groups are located in the range between 1025 and 900 cm−1 [36–38].
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2015, Journal of Solid State ChemistryCitation Excerpt :Bands around 900 cm−1 can be assigned to stretching modes of the [BO4]5− groups [35,42]. Bands at 1297, 1354, and 1406 cm−1 result from [BO3]3− vibrations [35–37]. Out-of-plane bending of the BO3 groups results in absorptions at ~700 cm−1 [43].
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