The mechanism of the addition of haloalkanes to alkenes in the presence of dichlorotris(triphenylphosphine)ruthenium(II), [RuCl2(PPh3)3]
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2007, Thin Films and NanostructuresCitation Excerpt :The highly active catalysts synthesized by this method also exhibited unusually low effective activation energy of carbon tetrachloride addition to olefins. The value of 50 kJ/mol, obtained for the reaction with octane-1, is substantially lower than the commonly observed activation energies of 80–100 kJ/mol [42]. The possible reason is that the appearance of highly active charged states in a catalyst makes different metals closer in their catalytic properties.
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