New glycosidation reaction 1: Combinational use of Cp2ZrCl2-AgClO4 for activation of glycosyl fluorides and application to highly β-selective gylcosidation of D-mycinose

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Abstract

The combination of Cp2MCl2-AgClO4, (M=Zr, Hf) is effective for the activation of glycosyl fluorides, which enables the highly β-selective glycoside formation of D-mycinose by performing the reaction in benzene.

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