Metal-oxygen vibration modes in the infra-red spectra of aluminium, gallium and indium tris-acetylacetonates
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2018, BioelectrochemistryCitation Excerpt :The multiple bands appeared between 1490 and 1600 cm−1 are corresponded to the coupling of NH bending to the CN stretching which are presented in both FOA and DFO molecules (Fig. 3C), and those appeared between 3000 and 3100 cm−1 are assigned to aromatic CH stretching vibrations of FOA component [41]. Finally the bands appeared around 1025 and 613 cm−1 are attributed to the NO stretching vibration [42] of DFO, and GaO stretching vibration [43] of Ga(III)-complex, respectively. These results in conjunction with those obtained by electrochemical (Sections 3.1.1) and XPS (3.1.2) support successful construction of the mixed nanostructures system on gold, Au-MPA-[DFO-Ga(III)]‖-[FOA].
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2017, International Journal of Biological MacromoleculesCitation Excerpt :The FTIR spectrum of MW-Cell-GA after Al3+ adsorption is also presented in Fig. 1. The band at 496 cm−l may assign to Al-O frequency [58]. The ν(CO) of the amide group observed at 1652 cm−1 is shifted to 1635 cm−1 due to the coordination of the carbonyl group with Al3+.
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