Metal-oxygen vibration modes in the infra-red spectra of aluminium, gallium and indium tris-acetylacetonates

https://doi.org/10.1016/0371-1951(61)80096-9Get rights and content

Abstract

A comparison has been made of the infra-red spectrum of aluminium, gallium and indium tris-acetdelylacetonates. Metal-oxygen vibration modes have been discussed and the metal-oxygen stretching frequency has been assigned for Al-O, Ga-O and In-O bonds in these complexes.

References (9)

  • K. Nakamoto et al.

    Nature

    (1959)
  • K. Nakamoto et al.

    J. Chem. Phys.

    (1960)
  • T. Shimanouchi

    J. Chem. Phys.

    (1949)
    T. Shimanouchi

    J. Chem. Phys.

    (1949)
    T. Shimanouchi

    J. Chem. Phys.

    (1949)
  • A. Forman et al.

    Mol. Phys.

    (1959)
There are more references available in the full text version of this article.

Cited by (40)

  • Controlled synthesis of mixed molecular nanostructures from folate and deferrioxamine-Ga(III) on gold and tuning their performance for cancer cells

    2018, Bioelectrochemistry
    Citation Excerpt :

    The multiple bands appeared between 1490 and 1600 cm−1 are corresponded to the coupling of NH bending to the CN stretching which are presented in both FOA and DFO molecules (Fig. 3C), and those appeared between 3000 and 3100 cm−1 are assigned to aromatic CH stretching vibrations of FOA component [41]. Finally the bands appeared around 1025 and 613 cm−1 are attributed to the NO stretching vibration [42] of DFO, and GaO stretching vibration [43] of Ga(III)-complex, respectively. These results in conjunction with those obtained by electrochemical (Sections 3.1.1) and XPS (3.1.2) support successful construction of the mixed nanostructures system on gold, Au-MPA-[DFO-Ga(III)]‖-[FOA].

  • Microwave assisted modification of cellulose by gallic acid and its application for removal of aluminium from real samples

    2017, International Journal of Biological Macromolecules
    Citation Excerpt :

    The FTIR spectrum of MW-Cell-GA after Al3+ adsorption is also presented in Fig. 1. The band at 496 cm−l may assign to Al-O frequency [58]. The ν(CO) of the amide group observed at 1652 cm−1 is shifted to 1635 cm−1 due to the coordination of the carbonyl group with Al3+.

View all citing articles on Scopus
View full text