Chapter 16 - Heterocyclic Thiazyl and Selenazyl Radicals; Synthesis and Applications in Solid State Architecture

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Abstract

A wide range of heterocyclic sulfur-nitrogen and selenium-nitrogen radicals have been characterized in recent years. Synthetic routes to these materials are summarized, and the modes of association which they exhibit in the solid state are illustrated. The potential use of these radicals as building blocks for low-dimensional molecular conductors is outlined, and some strategies for generating specific solid state architectures are explored. Recent attempts to prepare conductive materials from custom-built bifunctional 1, 2, 3, 5-dithia- and diselenadiazolyls are described.

6. References (162)

  • M.H. Palmer et al.

    Chem. Phys.

    (1989)
  • M. Bénard et al.

    Chem. Phys.

    (1986)
  • H.W. Roesky

    Chem. Soc. Rev.

    (1986)
  • C. Hsu et al.

    J. Chem. Phys.

    (1974)
  • H. Chandra et al.

    J. Chem. Soc., Dalton Trans.

    (1987)
  • T. Chivers et al.

    Inorg. Chem.

    (1984)
  • S.A. Fairhurst et al.

    J. Magn. Reson.

    (1979)
  • S. Rolfe et al.

    J. Org. Chem.

    (1979)
  • E. Dormann et al.

    J. Am. Chem. Soc.

    (1987)
  • T. Chivers

    Chem. Rev.

    (1985)
  • T. Chivers

    Acc. Chem. Res.

    (1984)
  • T. Chivers
  • The Gmelin Handbook of Inorganic Chemistry, Sulfur Nitrogen Compounds, Part 2, Springer Verlag,...
  • R.T. Oakley

    Prog. Inorg. Chem.

    (1988)
  • R.E. Hoffmeyer et al.

    Can. J. Chem.

    (1988)
  • M. Bénard et al.

    Can. J. Chem.

    (1985)
  • M. Bénard et al.

    Theor. Chim. Acta

    (1986)
  • W.G. Laidlaw et al.

    J. Comput. Chem.

    (1987)
  • W.G. Laidlaw et al.

    J. Mol. Struc. (Theochem.)

    (1988)
  • W.G. Laidlaw et al.

    J. Int. Quant. Chem.

    (1983)
  • W.G. Laildaw et al.
  • J.W. Waluk et al.

    Inorg. Chem.

    (1981)
  • J.W. Waluk et al.

    Inorg. Chem.

    (1981)
    J.W. Waluk et al.

    Inorg. Chem.

    (1982)
  • H.-P. Klein et al.

    Inorg. Chem.

    (1986)
  • R.T. Boeré et al.

    J. Am. Chem. Soc.

    (1987)
  • S.W. Liblong et al.

    Can. J. Chem.

    (1983)
  • T. Yamabe et al.

    J. Phys. Chem.

    (1979)
  • T. Chivers et al.

    Inorg. Chem.

    (1984)
  • T. Chivers et al.

    Inorg. Chem.

    (1984)
  • A.J. Banister

    Nature (London)

    (1972)
  • B.M. Gimarc et al.

    Pure Appl. Chem.

    (1980)
  • B.M. Gimarc et al.

    Inorg. Chim. Acta

    (1980)
  • A.W. Cordes et al.

    Inorg. Chem.

    (1986)
  • R.T. Boeré et al.

    J. Am. Chem. Soc.

    (1985)
  • R.T. Boeré et al.

    J. Am. Chem. Soc.

    (1987)
  • K.T. Bestari et al.

    J. Am. Chem. Soc.

    (1989)
  • A.W. Cordes et al.

    Inorg. Chem.

    (1989)
  • J.L. Morris et al.

    Chem. Soc. Rev.

    (1986)
  • P.F. Kelly et al.

    Polyhedron

    (1986)
  • T. Chivers et al.

    Polyhedron

    (1986)
  • R.L. Greene et al.

    Phys. Rev. Lett.

    (1975)
  • M.M. Labes et al.

    Chem. Rev.

    (1979)
  • A.J. Banister et al.

    J. Chem. Soc, Dalton Trans.

    (1986)
  • U. Demant et al.

    Z. Naturforsch

    (1986)
  • A.J. Banister et al.

    J. Chem. Soc., Dalton Trans.

    (1987)
  • H.-P. Fritz et al.

    Z. Naturforsch

    (1983)
  • O.J. Scherer et al.

    Z. Naturforsch

    (1982)
  • J.A. Dodge et al.

    J. Am. Chem. Soc.

    (1990)
  • W.M. Lau et al.

    J. Am. Chem. Soc.

    (1986)
  • A.J. Banister et al.

    J. Chem. Soc, Dalton Trans

    (1990)
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