The effects of secular disequilibrium on (U–Th)/He systematics and dating of Quaternary volcanic zircon and apatite
Introduction
Tephra deposits resulting from highly explosive eruptions commonly form distinctive stratigraphic and chronologic markers. Where tephras can be correlated over large areas, they are particularly useful for detailed correlations in both marine and terrestrial sequences and between them (e.g. [1], [2]). Many isotopic techniques are available for dating such rocks (e.g. [3]), but those used most routinely are radiocarbon dating, generally extending from >0.3 ka to <55 ka [4], [5]; K–Ar and 40Ar/39Ar dating, capable of measuring ages <2 ka in favorable circumstances (e.g. [6], [7]) which are relatively rare, and fission track dating of glass (e.g. [8]) and zircon (e.g. [9]) down to ∼100–200 ka. The usefulness of tephra deposits as time markers is often limited by a lack of suitable material to date with these techniques as well as by relatively poor dating precision. In this study, we investigate the (U–Th)/He method [10] as a potential new tool for dating young volcanic deposits. In particular, we consider the effects of U-series disequilibrium and present new (U–Th)/He analyses on apatite and zircon from three exposures of the widespread ∼340-ka Rangitawa Tephra in New Zealand.
Section snippets
(U–Th)/He ages under conditions of secular disequilibrium
(U–Th)/He dating is based on the ingrowth of 4He from 238U, 235U, and 232Th decay series. While for most applications it is appropriate to assume that all daughters in these series are in secular equilibrium, for dating of materials with young crystallization ages (<∼1 Ma), this assumption may not be valid [11]. Over relatively short time periods (<200 Myr) the amount of 4He produced in an accumulation time t under conditions of secular equilibrium can be approximated [12] as:
The Rangitawa Tephra test case
The Rangitawa Tephra, a widespread tephra erupted from the Taupo Volcanic Zone of New Zealand, provides a test case for He dating of young volcanic eruptions. On the basis of similarities in fission track age (FTA), glass shard chemistry, mineralogy and stratigraphic position, Kohn et al. [9] proposed this name for a mid-Pleistocene airfall rhyolite tephra. Rangitawa Tephra is a well-documented marker in marine and terrestrial sequences in New Zealand, and in adjacent ocean basins [2], [9], [20]
Conclusions
Zircons in young (<1 Ma) tephras contain sufficient U, Th, and He that precise (U–Th)/He ages can be determined even on single crystals. However, He ages computed assuming secular equilibrium in young zircons may be inaccurate. For a tephra such as that studied here, failure to recognize a 230Th deficit in the zircons could lead to a systematic underestimate of the eruption age, with the error decreasing from ∼30% at 100 kyr to 20% at 300 kyr to 10% at 500 kyr. The major uncertainty in
Acknowledgements
This study was supported by the Australian Research Council and a fellowship to K.A.F. from the David and Lucille Packard Foundation. K.A.F. thanks A. Gleadow and the University of Melbourne for hosting a sabbatical leave. Mary Reid, Ian Fletcher, Tim Elliot and Fin Stuart provided helpful comments on the manuscript.[BARD]
References (24)
Pleistocene volcanic eruptions in New Zealand recorded in deep sea sediments
Earth Planet. Sci. Lett.
(1968)Isothermal plateau fission track ages of hydrated glass shards from silicic tephra beds
Earth Planet. Sci. Lett.
(1989)- et al.
Zircon fission track age for middle Pleistocene Rangitawa Tephra, New Zealand
Paleogeogr. Paleoclimatol. Paleoecol.
(1992) Helium-Uranium dating of corals
Geochim. Cosmochim. Acta
(1973)- et al.
A sensitivity analysis of the apatite (U–Th)/He thermochronometer
Chem. Geol.
(1998) The effect of initial 230Th disequlibrium on young U–Pb ages: the Makalu case, Himalaya
Earth Planet. Sci. Lett.
(1984)- et al.
Evolution of the Laacher See magma chamber: evidence from SIMS and TIMS measurements of U–Th disequilibria in minerals and glasses
Earth Planet. Sci. Lett.
(1994) - et al.
Prolonged residence times for the youngest rhyolites associated with Long Valley Caldera 230Th–238U ion microprobe dating of young zircons
Earth Planet. Sci. Lett.
(1997) - et al.
Some remarks on U–Th mineral ages from igneous rocks with prolonged crystallization histories
Earth Planet. Sci. Lett.
(2000) - et al.
Multi-method dating comparison for mid-Pleistocene Rangitawa Tephra, New Zealand
Quat. Sci. Rev.
(1996)
Revision of the marine chronology in the Wanganui Basin, New Zealand, based on the isothermal fission-track dating of tephra horizons
Sediment. Geol.
The effects of long alpha-stopping distances on (U–Th)/He ages
Geochim. Cosmochim. Acta
Cited by (104)
Timing and recurrence intervals for voluminous silicic eruptions from Amatitlán caldera (Guatemala)
2023, Quaternary Science ReviewsCosmogenic <sup>3</sup>He in terrestrial rocks: A review
2021, Chemical GeologyConsiderations for double-dating zircon in secular disequilibrium with protracted crystallisation histories
2021, Chemical GeologyCitation Excerpt :The D230 and D231 values are parameters describing the fractionation of 230Th and 231Pa relative to U from the melt into zircon crystals. Calculation of D230 (Farley et al., 2002) was achieved by dividing the Th/U measured from individual crystals by the Th/U of the whole rock. This calculation assumes that the magma was in secular equilibrium at the time of zircon crystallisation and that the whole rock value of Th/U is the same as that of the magma from which the zircon crystallised.