Enantioselective synthesis of sec-allylalcohols by catalytic asymmetric addition of divinylzinc to aldehydes.
Ligand (2 mol%) catalyzes the addition of divinylzinc to aromatic and aliphatic aldehydes giving allylalcohols in 82 to 88% e.e. (with 20 mol% of : ~100% e.e.)
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