Polyhedron report number 19: Naked phosphorus atoms and units in transition-metal compounds
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P atom as ligand in transition metal chemistry: Structural aspects
2021, Coordination Chemistry ReviewsCitation Excerpt :In this contribution, we have centred the attention on phosphorus as single-atom ligand coordinated to one or more transition metals (TMs). Phosphorus has a rich chemistry and the interest in this element as ligand was early covered by several reviews at the end of the last century and the beginning of this one [1–9]. Di Vaira, Stoppioni, and Peruzzini, to whom was dedicated this paper, published one of the first examples of these contributions in 1987.
Phosphinidene-bridged binuclear complexes
2017, Coordination Chemistry ReviewsCitation Excerpt :A complex mixture of uncharacterised products was obtained in the related reaction with elemental selenium. A stable sulphide derivative, however, was obtained upon reaction of sulphur with the tetracarbonyl diiron complex [Fe2Cp2(μ-PPh)(CO)4] [90]. In a more systematic study, Ruiz and co-workers explored the reactivity of the diiron tricarbonyls 32 (R = Cy [85,42c], Ph [42c], Mes∗ [42b]) with different sources of oxygen atoms and sulphur to give the corresponding complexes 97 and 98 bearing P:P-bridging phosphinidene chalcogenide ligands (Scheme 53).
Inorganic metallocenes: The structures and aromaticity of sandwich compounds of the transition elements with inorganic rings
2011, Coordination Chemistry ReviewsCitation Excerpt :Another inverse sandwich compound, [{(η5-C5H5)Cr(CO)}(η3-P3)][{(η5-C5H5)Cr}2{μ-(η1:η5:η5-P5)}] (Fig. 26b) has two Cr atoms that are η5-bonded to either side of a distorted bridging cyclo-P5− unit that is also η1-bonded to a third Cr atom of a [(η5-C5H5)Cr(CO)](η3-P3) fragment [150]. Although no signals were observed in the EPR (130 K) and 31P (300 K) spectra, the fragmentation pattern in the mass spectrum of a brown solid isolated from toluene has been interpreted as showing the presence of a mixture of the inverse sandwich compounds [(η5-C5H5)Cr]2[μ-(η5:η5-PnAs5-n)] (n = 1–5) [56]. A DFT study has shown multiple σ-, π-, δ- and φ-aromaticity arising from U atom 5f orbital participation in the cyclo-U5 core of cyclo-U5(μ2-C)5 [10,76].
D<sup>6</sup> metal systems for white phosphorus activation
2010, Comptes Rendus ChimieCitation Excerpt :The reactivity of white phosphorus with transition metal complexes has been extensively investigated in the past few decades and a great variety of transition metal complexes, which contain Pn units originating from either the coupling or degradation of the cage molecule or from the recombination of smaller fragments into polyatomic aggregates, have been described. Such a research field has been exhaustively considered in some reviews [13–17]. Recently, the P4 molecule, which has dangerous environmental effects due to its high reactivity and toxicity, has received specific attention directed both to neutralize the dangerous effects and to achieve its functionalization in mild conditions, that could be of relevance to industrial processes.
A coordination chemistry approach towards ternary M/14/16 anions
2007, Coordination Chemistry Reviews